Curtin University Homepage
  • Library
  • Help
    • Admin

    espace - Curtin’s institutional repository

    JavaScript is disabled for your browser. Some features of this site may not work without it.
    View Item 
    • espace Home
    • espace
    • Curtin Theses
    • View Item
    • espace Home
    • espace
    • Curtin Theses
    • View Item

    Development of an electrostatically assisted solvent extraction column

    185452_Steffens2011.pdf (4.197Mb)
    Access Status
    Open access
    Authors
    Steffens, Marc J.
    Date
    2011
    Supervisor
    Prof. Don Ibana
    Type
    Thesis
    Award
    PhD
    
    Metadata
    Show full item record
    School
    Western Australian School of Mines, Department of Metallurgical and Minerals Engineering
    URI
    http://hdl.handle.net/20.500.11937/1934
    Collection
    • Curtin Theses
    Abstract

    Solvent extraction (SX) is the only commercially viable hydrometallurgical separation and purification technique for a range of metals that allows high product throughput and consistently high recoveries. After over 50 years of commercial application, however, limitations inherent to the mechanical agitation used within the most widely used commercial SX contactor – the mixer-settler – have become apparent. It is now generally accepted that mechanical agitation results in regions of high shear within the mixer, which favours the formation of crud, non-uniform droplet sizes and the formation of numerous ultra-fine droplets. The other commercially used contactor, the pulse column, does not suffer from as many problems as the mixer-settler but it is not suitable for systems with slow kinetics.A promising alternative to these mechanically agitated solvent extraction contactors are electrostatically agitated solvent extraction (ESX) contactors. Bench-scale studies indicate that these contactors allow higher rates of mass transfer, excellent control of droplet size, and lower shear agitation than mechanically agitated contactors. There are also suggestions that the technique requires only a fraction of the power relative to that of mechanical agitation. Despite these promising attributes, a commercial application has not been achieved. This may be attributed to a poor understanding of electrostatically-assisted droplet dispersion over a range of commercially applicable solution properties, the designs of ESX contactors already proposed being unsuitable for scale-up and the performance of an ESX contactor never having been evaluated on a pilot-scale.To better understand electrostatically-assisted droplet dispersion, a dispersion study that allowed the measurement of dispersed droplet sizes was carried out over a range of commercially applicable solution properties. To develop an ESX contactor suitable for scale-up and industrial application, various types of electrostatic field conditions were evaluated and numerous electrode designs were developed and evaluated. Finally, to evaluate the performance of the ESX contactor on a pilot-scale, a pilot-scale ESX column was constructed and its performance was compared to that of a sieve-plate pulse column, which was refurbished for this purpose. In pursuing the first objective it was found that: •The viscosity of both the solvent and the PLS, and the interfacial tension affect the droplet size distribution generated by electrostatic dispersion largely by affecting the number of ultra-fine droplets that form. The solvent conductivity affects droplet dispersion by affecting the degree of interfacial polarisation of the droplet. • Electrostatic droplet dispersion occurs either via a necking or jetting dispersion mechanism. In ESX, droplet dispersion by necking is favourable as it impedes the formation of ultra-fine droplets. The predominance of one mechanism over the other is influenced by the viscosity of the PLS and solvent.In pursuing the second objective it was found that: • An individual electrostatic PLS disperser is not appropriate for an industrially applicable ESX column. • Droplet motion within an electrostatic field is influenced by the electric charge that droplets carry and also by the strength and frequency of the electrostatic field. Increases in the charge of the droplet favours droplet motion and agitation; increases in the frequency of the electrostatic field favours droplet oscillation; decreases in the frequency of the electrostatic field favours droplet zigzagging. • A horizontal rod electrode arrangement within a column type contactor was found to be the most appropriate design for scale-up because it allowed (1) good droplet dispersion and agitation, (2) adequate aqueous fluxes to be achieved, and (3) coalescence of any ultra-fine droplets that form.In pursuing the third objective it was found that: • An electrostatic field strength of 6.5 kV/cm and electrostatic field frequency of 40 Hz yielded the highest extraction of nickel metal from sulphate/chloride solution. Under these conditions, the fluxes achieved within the ESX column were comparable to those used in pulsed columns. This is particularly significant as it disproves the commonly perceived main limitation of electrostatic dispersion. • Concurrent operation of the ESX and sieve-plate columns, each with an aqueous flux of 37 m³/h/m², revealed that the metal extraction achieved within each column was comparable, with a height equivalent to a theoretical stage (HETS) of 3.30 m. This demonstrates that ESX columns can handle industrially applicable aqueous fluxes. Further improvements in the ESX column design promise enhanced results.

    Related items

    Showing items related by title, author, creator and subject.

    • Extraction and separation of cobalt from acidic nickel laterite leach solutions using electrostatic pseudo liquid membrane (ESPLIM)
      Heckley, Philip Scott (2002)
      Approximately 70% of the western world's known nickel reserves are contained in laterite ores, but only 30% of the world's nickel production comes from these ores. This is due to the lack of economically viable technology ...
    • Electrostatic Agitation in Hydrometallurgical Solvent Extraction
      Ibana, Don; Steffens, Marc (2008)
      The use of mechanical agitation in solvent extraction (SX) provides limited capability to control droplet size, droplet size distribution, and droplet motion leading to poor mass transfer, inefficient phase separation, ...
    • Effect of electrostatic fields on mass transfer in solvent extraction
      Assmann, Simon (2014)
      An investigation on the effect of electrostatic fields on mass transfer was carried out in an effort toward development of a commercial application of electrostatic solvent extraction (ESX) in hydrometallurgy. The results ...
    Advanced search

    Browse

    Communities & CollectionsIssue DateAuthorTitleSubjectDocument TypeThis CollectionIssue DateAuthorTitleSubjectDocument Type

    My Account

    Admin

    Statistics

    Most Popular ItemsStatistics by CountryMost Popular Authors

    Follow Curtin

    • 
    • 
    • 
    • 
    • 

    CRICOS Provider Code: 00301JABN: 99 143 842 569TEQSA: PRV12158

    Copyright | Disclaimer | Privacy statement | Accessibility

    Curtin would like to pay respect to the Aboriginal and Torres Strait Islander members of our community by acknowledging the traditional owners of the land on which the Perth campus is located, the Whadjuk people of the Nyungar Nation; and on our Kalgoorlie campus, the Wongutha people of the North-Eastern Goldfields.