Exploring the Chemistry of Lanthanoid β–Triketonate Complexes
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This thesis reports the design, synthesis and characterisation of new β-triketonate based lanthanoid complexes. The use of systematically modified β-triketone molecules as ligands for these f-metal ions and their effect on the structural and photophysical properties of the complexes were investigated in detail. This study allowed a better understanding of the relationship between structure and photophysical activity of the lanthanoid complexes and the isolation of unusually efficient near-infrared emitters.
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