Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes

dc.relation.isnodouble	44708	*
dc.contributor.author	D'Alessio, Daniel Mark
dc.contributor.supervisor	Dr Max Massi
dc.contributor.supervisor	Prof. Mark Ogden
dc.date.accessioned	2017-01-30T09:54:44Z
dc.date.available	2017-01-30T09:54:44Z
dc.date.created	2015-10-12T03:06:44Z
dc.date.issued	2015
dc.identifier.uri	http://hdl.handle.net/20.500.11937/853
dc.description.abstract	Syntheses of the bis-, tris- and tetra-tetrazolato calix[4]arene ligands were performed from their corresponding nitrile derivatives. Mono-nuclear lanthanoid complexes were characterised in the presence of triethylamine, while addition of aqueous ammonium acetate resulted in the formation of an unprecedented discrete linear nineteen lanthanoid hydroxo cluster (Ln19). It was found the length of the cluster could be altered to an Ln12 structure, while retaining an identical cluster motif, by simply replacing ammonium acetate with ammonium benzoate.
dc.language	en
dc.publisher	Curtin University
dc.title	Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes
dc.type	Thesis
dcterms.educationLevel	PhD
curtin.department	Department of Chemistry
curtin.accessStatus	Open access