Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate
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Andrews, P.
Beck, T.
Forsyth, C.
Fraser, B.
Junk, P.
Massi, Massimiliano
Roesky, P.
Date
2007Type
Journal Article
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Andrews, Philip C. and Beck, Tobias and Forsyth, Craig M. and Fraser, Benjamin H. and Junk, Peter C. and Massi, Massimiliano and Roesky, Peter W. 2007. Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate. Dalton Transactions 48: pp. 5651-5654.
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Dalton Transactions
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Abstract
Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.