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    Ligand-induced structural, photophysical, and electrochemical variations in tricarbonyl rhenium(I) tetrazolato complexes

    192324_94322_P._Wright.pdf (2.851Mb)
    Access Status
    Open access
    Authors
    Wright, Phillip
    Affleck, M.
    Muzzioli, S.
    Skelton, B.
    Raiteri, Paolo
    Silvester, Debbie
    Stagni, S.
    Massi, Massimiliano
    Date
    2013
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Wright, Phillip J. and Affleck, Mark G. and Muzzioli, Sara and Skelton, Brian W. and Raiteri, Paolo and Silvester, Debbie S. and Stagni, Stefano and Massi, Massimiliano. 2013. Ligand-induced structural, photophysical, and electrochemical variations in tricarbonyl rhenium(I) tetrazolato complexes. Organometallics. 32 (13): pp. 3728-3737.
    Source Title
    Organometallics
    DOI
    10.1021/om400356n
    ISSN
    02767333
    Remarks

    Copyright © 2013 American Chemical Society

    URI
    http://hdl.handle.net/20.500.11937/10939
    Collection
    • Curtin Research Publications
    Abstract

    Treatment of [Re(CO)5X] (X = Cl, Br) with 2-(2-tert-butyltetrazol-5-yl)pyridine yielded neutral mononuclear complexes by exchange of two CO ligands for the chelating tetrazolato ligand. Treatment of [Re(CO)5Br] with phenyltetrazolate resulted in the assembly of an anionic dinuclear rhenium tricarbonyl species bridged by three tetrazole rings. The reaction of [Re(CO)5Br] with (2-tert-butyltetrazol-5-yl)benzene formed an analogous neutral dinuclear complex bridged by a tetrazole ring as well as two bromide ligands; however this complex was found to be rather unstable in solution and was only structurally characterized via X-ray diffraction. The first three complexes were investigated for their photophysical properties, highlighting phosphorescent emission from their triplet metal-to-ligand charge transfer excited states, although in the case of the dinuclear species the quantum yield was found to be extremely low. The complexes are also characterized for their electrochemical behavior, and while the neutral mononuclear species show irreversible oxidations, the dinuclear complex displays one reversible and simultaneous two-electron oxidation.

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