Fully Ir(iii) tetrazolate soft salts: the road to white-emitting ion pairs
MetadataShow full item record
The first examples of anionic Ir(iii) bis-tetrazolate complexes and their combination with a cationic Ir(iii)tetrazole derivative forming "fully tetrazolate" Ir(iii) based soft salts as O2-sensitive white emitters are described herein.
Showing items related by title, author, creator and subject.
Synthesis, photophysical and electrochemical investigation of dinuclear tetrazolato-bridged rhenium complexesWright, Phillip; Muzzioli, S.; Werrett, Melissa; Raiteri, Paolo; Skelton, B.; Silvester, Debbie; Stagni, S.; Massi, Massimiliano (2012)Starting from anionic tetrazole-based ligands, namely 5-(4’-cyanophenyl)tetrazolate and 5-(4’-pyridyl)tetrazolate, mononuclear and dinuclear complexes of fac-[Re(CO)3(phen)]+ (phen = 1,10-phenanthroline) were prepared and ...
Negatively charged Ir(III) cyclometalated complexes containing a chelating bis-tetrazolato ligand: Synthesis, photophysics and the study of reactivity with electrophilesFiorini, V.; Zacchini, S.; Raiteri, Paolo; Mazzoni, R.; Zanotti, V.; Massi, Massimiliano; Stagni, S. (2016)The bis-tetrazolate dianion [1,2 BTB]2−, which is the deprotonated form of 1,2 bis-(1H-tetrazol-5-yl)benzene [1,2-H2BTB], is for the first time exploited as an ancillary N^N ligand for negatively charged [Ir(C^N)2(N^N)]−-type ...
Proton-induced reversible modulation of the luminescent output of rhenium(I), iridium(III), and ruthenium(II) tetrazolate complexesWerrett, Melissa; Muzzioli, S.; Wright, Phillip; Palazzi, A.; Raiteri, Paolo; Zacchini, S.; Massi, Massimiliano; Stagni, S. (2014)One of the distinct features of metal–tetrazolate complexes is the possibility of performing electrophilic additions onto the imine-type nitrogens of the coordinated five-membered ring. These reactions, in particular, ...