New zinc and bismuth doped glass sealants with substantially suppressed boron deposition andpoisoning for solid oxide fuel cells
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Borosilicate-based glasses are the most common sealant materials for solid oxide fuel cells (SOFCs). However, boron species vaporizing from glass sealants poison and degrade the electrocatalytic activity of cathodes of SOFCs. In this study, we report the development of a new class of glass sealants based on bismuth and zinc doped borosilicates with significantly suppressed boron volatility. Doping Bi induces the [BO3] → [BO4] transition with an increased binding energy of boron, while addition of Zn leads to the formation of a boron-containing compound, Sr3B2SiO8, with significantly increased stability of boron in the glass matrix. Using La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) perovskite oxide as the cathode to assess the boron deposition and poisoning, the results indicate that the polarization performance of the LSCF cathode for the O2 reduction reaction in the presence of Bi and Zn doped glass is very stable with a negligible change in the microstructure of the electrodes. In contrast, in the case of conventional borosilicate glass, boron preferentially deposits in the electrode/electrolyte region under cathodic polarization, forming primarily LaBO3, disintegrating the perovskite structure and significantly degrading the electrochemical activity of the LSCF cathodes. Doping Bi or Zn remarkably reduces the boron volatility of the glass, thus effectively inhibiting the poisoning of boron species on the microstructure and electrocatalytic activity of SOFC cathodes such as LSCF. The present results demonstrate for the first time that the Bi and Zn doping is the most effective strategy to minimize the boron poisoning from the source by suppressing the boron vaporization of borosilicate-based glass sealant materials.
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Effects of Nb2O5 and Gd2O3 doping on boron volatility and activity between glass seals and lanthanum-containing cathodeZhang, Q.; Chen, Kongfa; Tang, D.; Zhang, T.; Jiang, San Ping (2017)In planar Solid Oxide Fuel Cells (SOFCs), the boron species volatilize from glass seals, and react with lanthanum-containing cathodes (i.e., La0.6Sr0.4Co0.2Fe0.8O3 - d, LSCF) to form LaBO3 under cathodic polarization, ...
A Fundamental Study of Boron Deposition and Poisoning of La0.8Sr0.2MnO3 Cathode of Solid Oxide Fuel Cells under Accelerated ConditionsChen, K.; Liu, S.; Guagliardo, P.; Kilburn, M.; Koyama, M.; Jiang, San Ping (2015)Borosilicate glass and glass-ceramics are the most common sealant materials for planar solid oxide fuel cells (SOFCs). This study focuses on the fundamentals of deposition and poisoning of volatile boron species from the ...
Effect of Volatile Boron Species on the Electrocatalytic Activity of Cathodes of Solid Oxide Fuel Cells: III. Ba0.5Sr0.5Co0.8Fe0.2O3-δ ElectrodesChen, Kongfa; Hyodo, J.; O'Donnell, Kane; Rickard, William; Ishihara, T.; Jiang, San Ping (2014)The effect of volatile boron species on the electrocatalytic activity, microstructure and phase stability of Ba0.5Sr0.5Co0.8Fe0.2O3-d (BSCF) cathodes has been studied. The cathodes were heat-treated at 800?C for 7 days ...