Activation of DMSO for Swern-type oxidation by 1,1-dichlorocycloheptatriene
Access Status
Authors
Date
2014Collection
Type
Metadata
Show full item recordAbstract
A new dimethylsulfoxide activation method employing 1,1-dichlorocycloheptatriene has been developed for a mild Swern-type oxidation of a variety of alcohols. The carbonyl products can be obtained in good to excellent yields from this operationally simple and efficient method. This work is the first report of dimethylsulfoxide activation by a simple chlorinated hydrocarbon reagent, which has the unique ability of equilibrating to its reactive aromatic cationic form.
Citation
Source Title
School
Remarks
NOTICE: this is the author’s version of a work that was accepted for publication in the journal Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in the journal Tetrahedron Letters, Vol.55, No.50 (2014). DOI: http://doi.org/10.1016/j.tetlet.2014.10.100
Related items
Showing items related by title, author, creator and subject.
-
Fansuri, Hamzah (2005)Bismuth molybdates have long been known as active catalysts for selective oxidation of olefins. There are several phases of bismuth molybdates but only three of them are known to be active for partial oxidation of propylene ...
-
Shukla, Pradeep (2010)This dissertation explores a combined adsorption and advanced oxidation technology for trapping and destruction of organic pollutants in waste water. The adsorbed/immobilized pollutant onto the surface of metal supported ...
-
Warton, Benjamin (1999)This thesis reports the results of investigations carried out into the composition of the saturate and aromatic unresolved complex mixtures (UCMs) in crude oils. It is divided into two sections. Section A reports on studies ...