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    Small molecules induce mesocrystal formation: nanoparticle aggregation directed by self-assembling calixarenes

    151833_25180_Small Molecules Induce Mesocrystal Formation Nanoparticle.pdf (4.001Mb)
    Access Status
    Open access
    Authors
    Baynton, A.
    Radomirovic, Tomoko
    Ogden, Mark
    Raston, C.
    Richmond, William
    Jones, Franca
    Date
    2010
    Type
    Journal Article
    
    Metadata
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    Citation
    Baynton, Andrew and Radomirovic, Tomoko and Ogden, Mark I. and Raston, Colin L. and Richmond, William R. and Jones, Franca. 2011. Small molecules induce mesocrystal formation: nanoparticle aggregation directed by self-assembling calixarenes. CrystEngComm. 13 (1): pp. 109-112.
    Source Title
    CrystEngComm
    DOI
    10.1039/C0CE00579G
    ISSN
    14668033
    School
    Department of Applied Chemistry
    URI
    http://hdl.handle.net/20.500.11937/12834
    Collection
    • Curtin Research Publications
    Abstract

    Calixarenes have been shown to induce mesocrystal formation of barium sulfate, despite being relatively low molecular weight additives. Scanning probe microscopy has shown that a possible mechanism is the self-assembling properties of the calixarene resulting in steric stabilization of the nanoparticles, comparable to that typically requiring polymeric additives.

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