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Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion

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Authors
Baker, M.
Brown, David
Hesler, V.
Skelton, B.
White, A.
Date
2007
Type
Journal Article

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Baker, M. and Brown, D. and Hesler, V. and Skelton, B. and White, A. 2007. Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion. Organometalllics. 26: pp. 250-252.
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Organometalllics
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Abstract

The formation of a cyclophane-NHC complex of Pd-(II) Via oxidatiVe addition of a C-C bond in a bridged biimidazolium ion to Pd(0) is described. The actiVe Pd(0) species appears to be [Pd(PPh3)2Br]-. Simple (unbridged) biimidazolium ions do not form NHC complexes under similar conditions.