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    Thermodynamic Difference Rules: A Prescription for Their Application and Usage to Approximate Thermodynamic Data

    Access Status
    Fulltext not available
    Authors
    Jenkins, H.
    Glasser, Leslie
    Date
    2010
    Type
    Journal Article
    
    Metadata
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    Citation
    Jenkins, H. Donald Brooke and Glasser, Leslie. 2010. Thermodynamic Difference Rules: A Prescription for Their Application and Usage to Approximate Thermodynamic Data. Journal of Chemical & Engineering Data. 55 (10): pp. 4231-4238.
    Source Title
    Journal of Chemical & Engineering Data
    DOI
    10.1021/je100383t
    ISSN
    00219568
    Faculty
    Nanochemistry Research Institute (NRI)
    Faculty of Science and Engineering
    School
    Nanochemistry Research Institute (Research Institute)
    URI
    http://hdl.handle.net/20.500.11937/13034
    Collection
    • Curtin Research Publications
    Abstract

    Thermodynamic data are required for an understanding of the behavior of materials but are often lacking(or even unreliable) for a variety of reasons such as synthetic problems, purity issues, failure to correctlyidentify hydrolysis products, instability of the material, etc. Thus, it is necessary to develop procedures for the estimation of that data. The Thermodynamic Difference Rules (TDR) are additive approximations by which the properties of materials are estimated by reference to those of related materials. These rules appear in the form of the reliable Hydrate Difference Rule (HDR), based on the well-established properties of the large number of known hydrates, and the somewhat less certain Solvate Difference Rule (SDR). These rules are briefly surveyed and their application carefully delineated by a scheme and demonstrated by a number of calculated examples.

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