Silver(I) and mercury(II) complexes of meta- and para-xylyl linked bis(imidazol-2-ylidenes)
| dc.contributor.author | Baker, M. | |
| dc.contributor.author | Brown, David | |
| dc.contributor.author | Haque, R. | |
| dc.contributor.author | Skelton, B. | |
| dc.contributor.author | White, A. | |
| dc.date.accessioned | 2017-01-30T11:37:52Z | |
| dc.date.available | 2017-01-30T11:37:52Z | |
| dc.date.created | 2009-09-21T20:02:32Z | |
| dc.date.issued | 2009 | |
| dc.identifier.citation | Baker, Murray and Brown, David and Haque, Rosenani and Skelton, Brian and White, Allan. 2009. Silver(I) and mercury(II) complexes of meta- and para-xylyl linked bis(imidazol-2-ylidenes). Journal of Inclusion Phenomena and Macrocyclic Chemistry. 65 (1-2): pp. 97-109. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/13551 | |
| dc.identifier.doi | 10.1007/s10847-009-9633-7 | |
| dc.description.abstract |
Mononuclear silver and mercury complexes bearing bis-N-heterocyclic carbene (NHC) ligands withlinear coordination modes have been prepared and structurally characterised. The complexes form metallocyclic structures that display rigid solution behaviour. A larger metallocycle of the form [L2Ag2]2+ [where L = parabis(N-methylimidazolylidene)xylylene] has been isolated from the reaction of para-xylylene-bis(N-methylimidazolium) chloride and Ag2O. Reaction of silver- and mercury-NHC complexes with Pd(NCCH3)2Cl2 affords palladium-NHC complexes via NHC-transfer reactions, the mercury case being only the second example of a NHC-transfer reaction using a mercury-NHC complex. | |
| dc.publisher | Springer Netherlands | |
| dc.subject | N-Heterocyclic carbenes - Carbene transfer | |
| dc.subject | Silver - Mercury | |
| dc.title | Silver(I) and mercury(II) complexes of meta- and para-xylyl linked bis(imidazol-2-ylidenes) | |
| dc.type | Journal Article | |
| dcterms.source.volume | 65 | |
| dcterms.source.number | 1-2 | |
| dcterms.source.startPage | 97 | |
| dcterms.source.endPage | 109 | |
| dcterms.source.issn | 09230750 | |
| dcterms.source.title | Journal of Inclusion Phenomena and Macrocyclic Chemistry | |
| curtin.note |
The original publication is available at: | |
| curtin.accessStatus | Open access | |
| curtin.faculty | Department of Applied Chemistry | |
| curtin.faculty | Nanochemistry Research Institute (Research Institute) | |
| curtin.faculty | School of Science | |
| curtin.faculty | Faculty of Science and Engineering |