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    The role of aromatic precursors in the formation of haloacetamides by chloramination of dissolved organic matter

    Access Status
    Fulltext not available
    Authors
    Le Roux, J.
    Nihemaiti, M.
    Croue, Jean-Philippe
    Date
    2016
    Type
    Journal Article
    
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    Citation
    Le Roux, J. and Nihemaiti, M. and Croue, J. 2016. The role of aromatic precursors in the formation of haloacetamides by chloramination of dissolved organic matter. Water Research. 88: pp. 371-379.
    Source Title
    Water Research
    DOI
    10.1016/j.watres.2015.10.036
    ISSN
    0043-1354
    School
    Curtin Water Quality Research Centre
    URI
    http://hdl.handle.net/20.500.11937/13930
    Collection
    • Curtin Research Publications
    Abstract

    Water treatment utilities are diversifying their water sources and often rely on waters enriched in nitrogen-containing compounds (e.g., ammonia, organic nitrogen such as amino acids). The disinfection of waters exhibiting high levels of nitrogen has been associated with the formation of nitrogenous disinfection byproducts (N-DBPs) such as haloacetonitriles (HANs) and haloacetamides (HAcAms). While the potential precursors of HANs have been extensively studied, only few investigations are available regarding the nature of HAcAm precursors. Previous research has suggested that HAcAms are hydrolysis products of HANs. Nevertheless, it has been recently suggested that HAcAms can be formed independently, especially during chloramination of humic substances. When used as a disinfectant, monochloramine can also be a source of nitrogen for N-DBPs. This study investigated the role of aromatic organic matter in the formation of N-DBPs (HAcAms and HANs) upon chloramination. Formation kinetics were performed from various fractions of organic matter isolated from surface waters or treated wastewater effluents. Experiments were conducted with 15N-labeled monochloramine (15NH2Cl) to trace the origin of nitrogen. N-DBP formation showed a two-step profile: (1) a rapid formation following second-order reaction kinetics and incorporating nitrogen atom originating from the organic matrix (e.g., amine groups); and (2) a slower and linear increase correlated with exposure to chloramines, incorporating inorganic nitrogen (15N) from 15NH2Cl into aromatic moieties. Organic matter isolates showing high aromatic character (i.e., high SUVA) exhibited high reactivity characterized by a major incorporation of 15N in N-DBPs. A significantly lower incorporation was observed for low-aromatic-content organic matter. 15N-DCAcAm and 15N-DCAN formations exhibited a linear correlation, suggesting a similar behavior of 15N incorporation as SUVA increases. Chloramination of aromatic model compounds (i.e., phenol and resorcinol) showed higher HAcAm and HAN formation potentials than nitrogenous precursors (i.e., amino acids) usually considered as main precursors of these N-DBPs. These results demonstrate the importance of aromatic organic compounds in the formation of N-DBPs, which is of significant importance for water treatment facilities using chloramines as final disinfectant.

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