One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation

Wright, Phillip; Muzzioli, S.; Skelton, B.; Raiteri, Paolo; Lee, J.; Koutsantonis, G.; Silvester, Debbie; Stagni, S.; Massi, Massimiliano

doi:10.1039/c3dt50988e

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Authors

Wright, Phillip

Muzzioli, S.

Skelton, B.

Raiteri, Paolo

Lee, J.

Koutsantonis, G.

Silvester, Debbie

Stagni, S.

Massi, Massimiliano

Date

2013

Type

Journal Article

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Abstract

The reaction of 2-pyridyltetrazolate with [Re(CO)5X] (X = Cl, Br) yielded the formation of an unexpected cyclic metallacalix[3]-arene, as revealed by X-ray structural studies, characterised by aqua emission and reversible three-electron oxidation.

Citation

Wright, Phillip J. and Muzzioli, Sara and Skelton, Brian W. and Raiteri, Paolo and Lee, Jackson and Koutsantonis, George and Silvester, Debbie S. and Stagni, Stefano and Massi, Massimiliano. 2013. One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation. Dalton Transactions. 42 (23): pp. 8188-8191.

Source Title

Dalton Transactions

URI

http://hdl.handle.net/20.500.11937/15885

DOI

10.1039/c3dt50988e

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