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    Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide

    19324_downloaded_stream_416.pdf (497.0Kb)
    Access Status
    Open access
    Authors
    Ogden, Mark
    Skelton, B.
    White, A.
    Date
    2005
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Ogden, Mark I. and Skelton, Brian W. and White, Allan H.. 2005. Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide. Comptes Rendus Chimie 8 (2): 181-187.
    Source Title
    Comptes Rendus Chimie
    DOI
    10.1016/j.crci.2004.10.019
    Faculty
    Nanochemistry Research Centre
    School
    Nanochemistry Research Institute
    Remarks

    Journal Home Page: http://www.sciencedirect.com/science/journal/16310748

    URI
    http://hdl.handle.net/20.500.11937/17105
    Collection
    • Curtin Research Publications
    Abstract

    The coordination chemistry of amide-substituted calixarenes is reviewed. The synthesis of a gadolinium complex of a trisamide calix[4]arene is described, involving the reaction of 5,11,17,23-tetra-tert-butyl-24-hydroxy-26,27,28-tris(diethylcarbamoylmethoxy) calix[4]arene (L) with gadolinium picrate dodecahydrate. Structural studies demonstrated that the complex can be formulated as [(pic-O)Gd{(L H)(EtOH)}](pic)2 EtOH.

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