Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification
Access Status
Fulltext not available
Authors
Pei, Y.
Noy, J.
Roth, P.
Lowe, Andrew
Date
2015Collection
Type
Journal Article
Metadata
Show full item recordAbstract
RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles.
Citation
Pei, Y. and Noy, J. and Roth, P. and Lowe, A. 2015. Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification. Polymer Chemistry. 6 (11): pp. 1928-1931.
Source Title
Polymer Chemistry
Related items
Showing items related by title, author, creator and subject.
-
Zhu, Y.; Noy, J.; Lowe, Andrew; Roth, P. (2015)Polysulfobutylbetaine (SBB) (co)polymers, zwitterionic species bearing ammonium and sulfonate groups separated by a butyl spacer in every repeat unit, were prepared through three different synthetic routes and their aqueous ...
-
Pei, Y.; Dharsana, N.; Lowe, Andrew (2015)The ethanolic reversible addition-fragmentation chain transfer dispersion polymerization (RAFTDP), at 21 wt-%, of 2-(naphthalen-2-yloxy)ethyl methacrylate (NOEMA) and 2-phenoxyethyl methacrylate (POEMA) with a poly[2- ...
-
Pei, Y.; Dharsana, N.; van Hensbergen, J.; Burford, R.; Roth, Peter; Lowe, Andrew (2014)The direct synthesis of methacrylic-based soft polymeric nanoparticles via reversible addition–fragmentation chain transfer dispersion polymerization (RAFTDP) is described. The use of poly[2-(dimethylamino)ethyl methacrylate]s, ...