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    Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification

    Access Status
    Fulltext not available
    Authors
    Pei, Y.
    Noy, J.
    Roth, P.
    Lowe, Andrew
    Date
    2015
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Pei, Y. and Noy, J. and Roth, P. and Lowe, A. 2015. Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification. Polymer Chemistry. 6 (11): pp. 1928-1931.
    Source Title
    Polymer Chemistry
    DOI
    10.1039/c4py01558d
    ISSN
    1759-9954
    URI
    http://hdl.handle.net/20.500.11937/17563
    Collection
    • Curtin Research Publications
    Abstract

    RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles.

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