Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification
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Pei, Y.
Noy, J.
Roth, P.
Lowe, Andrew
Date
2015Type
Journal Article
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Pei, Y. and Noy, J. and Roth, P. and Lowe, A. 2015. Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification. Polymer Chemistry. 6 (11): pp. 1928-1931.
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Polymer Chemistry
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Abstract
RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles.
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