Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification
Abstract
RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles.
Citation
Pei, Y. and Noy, J. and Roth, P. and Lowe, A. 2015. Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification. Polymer Chemistry. 6 (11): pp. 1928-1931.
Source Title
Polymer Chemistry
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