Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand
| dc.contributor.author | Brown, David | |
| dc.contributor.author | Nealon, Gareth | |
| dc.contributor.author | Simpson, P. | |
| dc.contributor.author | Skelton, B. | |
| dc.contributor.author | Wang, Zhisen | |
| dc.date.accessioned | 2017-01-30T12:06:51Z | |
| dc.date.available | 2017-01-30T12:06:51Z | |
| dc.date.created | 2009-03-22T18:01:36Z | |
| dc.date.issued | 2009 | |
| dc.identifier.citation | Brown, David and Nealon, Gareth and Simpson, Peter and Skelton, Brian and Wang, Zhisen. 2009. Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand. Organometallics 28 (6): pp. 1965-1968. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/18254 | |
| dc.description.abstract |
Reaction of 2,6-bis(3-butylbenzimidazol-1-ium)pyridine dibromide with silVer oxide affords a dinuclear complex of the type [L2Ag2]2+ [L ) 2,6-bis(3-butylbenzimidazolin-2-ylidene)pyridine]. 1H NMR spectroscopic studies suggest that the dinuclear structure is also present in solution. Transmetalationof the silVer-NHC complex with PdCl2(CH3CN)2 yields a mononuclear palladium complex of the type [LPdCl]+, with a chelating C,N,C pincer ligand. | |
| dc.publisher | ACS Publications | |
| dc.relation.uri | http://pubs.acs.org/doi/full/10.1021/om801144m | |
| dc.relation.uri | http://pubs.acs.org/toc/orgnd7/28/6 | |
| dc.title | Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand | |
| dc.type | Journal Article | |
| dcterms.source.volume | 28 | |
| dcterms.source.number | 6 | |
| dcterms.source.startPage | 1965 | |
| dcterms.source.endPage | 1968 | |
| dcterms.source.issn | 02767333 | |
| dcterms.source.title | Organometallics | |
| curtin.accessStatus | Open access | |
| curtin.faculty | School of Engineering | |
| curtin.faculty | Nanochemistry Research Institute (Research Institute) |