Deprotonation of large calixarenes-cation binding and conformations
| dc.contributor.author | Harrowfield, J. | |
| dc.contributor.author | Koutsantonis, G. | |
| dc.contributor.author | Ogden, Mark | |
| dc.contributor.author | Sobolev, A. | |
| dc.contributor.author | White, A. | |
| dc.date.accessioned | 2017-01-30T12:06:56Z | |
| dc.date.available | 2017-01-30T12:06:56Z | |
| dc.date.created | 2016-06-12T19:30:26Z | |
| dc.date.issued | 2016 | |
| dc.identifier.citation | Harrowfield, J. and Koutsantonis, G. and Ogden, M. and Sobolev, A. and White, A. 2016. Deprotonation of large calixarenes-cation binding and conformations. Australian Journal of Chemistry. 69 (5): pp. 546-554. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/18274 | |
| dc.identifier.doi | 10.1071/CH15761 | |
| dc.description.abstract |
© 2016 CSIRO. Single crystal X-ray studies of p-t-butylcalix[10]arene·2dmso·7H2O (1) and [NMe4][p-t-butylcalix[9]arene-H]·2dmso·H2O (2), provide new data on these large macrocycles and their conformations, that of 2 being the first where an encapsulated [NMe4]+ cation is present, while 1 contains the neutral ligand. Both were obtained as crystalline products of the reactions of the calixarenes with tetramethylammonium hydroxide after prolonged standing. The structure of [NEt4][calix[4]arene-H], in which the cation approaches inclusion in the shallow cone of the anion, is also defined and compared with various other alkylammonium derivatives of calixarenes as well as that of p-t-butylcalix[9]arene. | |
| dc.publisher | CSIRO Publishing | |
| dc.title | Deprotonation of large calixarenes-cation binding and conformations | |
| dc.type | Journal Article | |
| dcterms.source.volume | 69 | |
| dcterms.source.number | 5 | |
| dcterms.source.startPage | 546 | |
| dcterms.source.endPage | 554 | |
| dcterms.source.issn | 0004-9425 | |
| dcterms.source.title | Australian Journal of Chemistry | |
| curtin.department | Department of Chemistry | |
| curtin.accessStatus | Open access |