Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV)
| dc.contributor.author | Harrowfield, J. | |
| dc.contributor.author | Ogden, Mark | |
| dc.contributor.author | Skelton, B. | |
| dc.contributor.author | White, A. | |
| dc.date.accessioned | 2017-01-30T12:07:43Z | |
| dc.date.available | 2017-01-30T12:07:43Z | |
| dc.date.created | 2008-11-12T23:25:22Z | |
| dc.date.issued | 2004 | |
| dc.identifier.citation | Harrowfield, Jack and Ogden, Mark and Skelton, Brian and White, Allan. 2004. Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV). Inorganica Chimica Acta 357 (8): 2404-2406. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/18415 | |
| dc.identifier.doi | 10.1016/j.ica.2004.01.030 | |
| dc.description.abstract |
The dimethylsulfoxide (dmso) solvate of Th(IV) perchlorate is readily obtained from acidic aqueous Th(IV) solutions and has a formulation established from a single crystal structure determination of [Th(dmso-O)9](ClO4)4 . 4dmso; triclinic, P1, a = 12:4811(8)A, b = 12:4879(8)A, c = 23:969(2)A, a = 94:684(1), b = 95:823(1), y = 119:347(1). The primary coordination sphere of the Th is of tricapped trigonal prismatic form, with the symmetry of the [Th(dmso-O)9] entity being close to C3h. | |
| dc.publisher | Elsevier | |
| dc.subject | Homoleptic dmso complex | |
| dc.subject | Thorium | |
| dc.subject | Nine-coordination | |
| dc.subject | Crystal structure | |
| dc.title | Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) | |
| dc.type | Journal Article | |
| dcterms.source.volume | 357 | |
| dcterms.source.number | 8 | |
| dcterms.source.startPage | 2404 | |
| dcterms.source.endPage | 2406 | |
| dcterms.source.title | Inorganica Chimica Acta | |
| curtin.department | Department of Applied Chemistry | |
| curtin.identifier | EPR-2284 | |
| curtin.accessStatus | Fulltext not available | |
| curtin.faculty | Division of Engineering, Science and Computing | |
| curtin.faculty | Faculty of Science |