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dc.contributor.authorNealon, Gareth
dc.contributor.authorMocerino, Mauro
dc.contributor.authorOgden, Mark
dc.contributor.authorSkelton, B.
dc.date.accessioned2017-01-30T12:08:50Z
dc.date.available2017-01-30T12:08:50Z
dc.date.created2015-03-03T20:17:45Z
dc.date.issued2009
dc.identifier.citationNealon, G. and Mocerino, M. and Ogden, M. and Skelton, B. 2009. The impact of the lanthanide contraction on the structure of complexes of a calix[4]arene trisamide. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 65: pp. 25-30.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/18613
dc.identifier.doi10.1007/s10847-009-9613-y
dc.description.abstract

The syntheses of samarium, holmium, and ytterbium complexes of a tris-amide calix[4]arene are described, and the resulting structures are compared with the previously reported gadolinium complex. The syntheses involved the reaction of 5,11,17,23-tetra-tert-butyl-24-hydroxy-26,27,28- tris(diethylcarbamoylmethoxy)calix[4]arene with the appropriate lanthanide picrate hydrate. Structural studies demonstrated that a picrate anion acts as a quasi-bidentate ligand with Sm (and Gd), is unidentate in the Ho complex, but is found in the second coordination sphere for the smallest lanthanide cation (Yb) investigated.

dc.publisherKluwer Academic Publishers
dc.titleThe impact of the lanthanide contraction on the structure of complexes of a calix[4]arene trisamide
dc.typeJournal Article
dcterms.source.volume65
dcterms.source.startPage25
dcterms.source.endPage30
dcterms.source.issn09230750
dcterms.source.titleJournal of Inclusion Phenomena and Macrocyclic Chemistry
curtin.note

The final publication is available at Springer via 10.1007/s10847-009-9613-y

curtin.departmentNanochemistry Research Institute
curtin.accessStatusOpen access


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