The impact of the lanthanide contraction on the structure of complexes of a calix[4]arene trisamide
| dc.contributor.author | Nealon, Gareth | |
| dc.contributor.author | Mocerino, Mauro | |
| dc.contributor.author | Ogden, Mark | |
| dc.contributor.author | Skelton, B. | |
| dc.date.accessioned | 2017-01-30T12:08:50Z | |
| dc.date.available | 2017-01-30T12:08:50Z | |
| dc.date.created | 2015-03-03T20:17:45Z | |
| dc.date.issued | 2009 | |
| dc.identifier.citation | Nealon, G. and Mocerino, M. and Ogden, M. and Skelton, B. 2009. The impact of the lanthanide contraction on the structure of complexes of a calix[4]arene trisamide. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 65: pp. 25-30. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/18613 | |
| dc.identifier.doi | 10.1007/s10847-009-9613-y | |
| dc.description.abstract |
The syntheses of samarium, holmium, and ytterbium complexes of a tris-amide calix[4]arene are described, and the resulting structures are compared with the previously reported gadolinium complex. The syntheses involved the reaction of 5,11,17,23-tetra-tert-butyl-24-hydroxy-26,27,28- tris(diethylcarbamoylmethoxy)calix[4]arene with the appropriate lanthanide picrate hydrate. Structural studies demonstrated that a picrate anion acts as a quasi-bidentate ligand with Sm (and Gd), is unidentate in the Ho complex, but is found in the second coordination sphere for the smallest lanthanide cation (Yb) investigated. | |
| dc.publisher | Kluwer Academic Publishers | |
| dc.title | The impact of the lanthanide contraction on the structure of complexes of a calix[4]arene trisamide | |
| dc.type | Journal Article | |
| dcterms.source.volume | 65 | |
| dcterms.source.startPage | 25 | |
| dcterms.source.endPage | 30 | |
| dcterms.source.issn | 09230750 | |
| dcterms.source.title | Journal of Inclusion Phenomena and Macrocyclic Chemistry | |
| curtin.note |
The final publication is available at Springer via 10.1007/s10847-009-9613-y | |
| curtin.department | Nanochemistry Research Institute | |
| curtin.accessStatus | Fulltext not available |