A Perovskite Electrocatalyst for Efficient Hydrogen Evolution Reaction

Xu, X.; Chen, Y.; Zhou, W.; Zhu, Z.; Su, C.; Liu, M.; Shao, Zongping

doi:10.1002/adma.201600005

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Authors

Xu, X.

Chen, Y.

Zhou, W.

Zhu, Z.

Su, C.

Liu, M.

Shao, Zongping

Date

2016

Type

Journal Article

Metadata

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Citation

Xu, X. and Chen, Y. and Zhou, W. and Zhu, Z. and Su, C. and Liu, M. and Shao, Z. 2016. A Perovskite Electrocatalyst for Efficient Hydrogen Evolution Reaction. Advanced Materials.

Source Title

Advanced Materials

DOI

10.1002/adma.201600005

ISSN

0935-9648

School

Department of Chemical Engineering

URI

http://hdl.handle.net/20.500.11937/19371

Collection

Curtin Research Publications

Abstract

Perovskite oxides are demonstrated for the first time as efficient electrocatalysts for the hydrogen evolution reaction (HER) in alkaline solutions. A-site praseodymium-doped Pr0.5 (Ba0.5 Sr0.5 )0.5 Co0.8 Fe0.2 O3- d (Pr0.5BSCF) exhibits dramatically enhanced HER activity and stability compared to Ba0.5 Sr0.5 Co0.8 Fe0.2 O3- d (BSCF), superior to many well-developed bulk/nanosized nonprecious electroctatlysts. The improved HER performance originates from the modified surface electronic structures and properties of Pr0.5BSCF induced by the Pr-doping.