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    The effect of grain orientation on secondary ion mass spectrometry (SIMS) analysis of rutile

    Access Status
    Fulltext not available
    Authors
    Taylor, Rich
    Clark, Chris
    Reddy, Steven
    Date
    2012
    Type
    Journal Article
    
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    Citation
    Taylor, Rich and Clark, Chris and Reddy, Steven. 2012. The effect of grain orientation on secondary ion mass spectrometry (SIMS) analysis of rutile. Chemical Geology 300-301: pp. 81-87.
    Source Title
    Chemical Geology
    DOI
    10.1016/j.chemgeo.2012.01.013
    ISSN
    0009-2541
    URI
    http://hdl.handle.net/20.500.11937/20137
    Collection
    • Curtin Research Publications
    Abstract

    In situ high precision U–Pb analysis of rutile by secondary ion mass spectrometry (SIMS) reveals that instrumental bias for isotope ratios and count rates vary due to crystal orientation. Electron backscatter diffraction (EBSD) techniques have been combined with SIMS data to show consistent and systematic crystal orientation effects, whilst confirming that all analyses are on single crystals and that there is random variation from grain to grain. The result of the orientation effect is to produce an extremely large calibration slope, more than an order of magnitude larger than for other minerals, which can result in highly inaccurate and spurious U–Pb ages from rutile if not taken into account. We present a large standard dataset to highlight this effect and show that by collecting good standard data, from grains in multiple orientations, these effects can be negated and accurate U–Pb SIMS data for rutile can be obtained using a standard calibration slope of ln(Pb+/U+) vs ln(UO2+/UO+)=1.12. Examples from the Anantangiri region, Eastern Ghats, India are used to show the magnitude of these effects on the calibration of unknowns. Evidence is presented to show that the cause of these orientation effects is most likely a combination of channelling of primary ions into the crystal and preferential emission of secondary ions along preferred lattice directions.

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