SrCe0.95Y0.05O3-δ-ZnO dual-phase membranes for hydrogen permeation
MetadataShow full item record
A hydrogen permeation membrane plays a key role in membrane reactor applications for hydrogen production. To this end, a SrCe0.95Y0.05O3-δ (SCY) proton conductor has been regarded as an attractive candidate. This work aimed to increase the practical value of SCY by making its composite with ZnO. The presence of ZnO was found to increase the sinterability of SCY, resulting in a 200 °C reduction in the sintering temperature required to obtain a dense membrane as normally achieved at 1400 °C. The electrical conductivities of the composites in a hydrogen atmosphere were also enhanced by the addition of ZnO. The fact that the sintering of the composite membrane at 1200 °C leads to the formation of a dense composite body while not resulting in the formation of new phases detectable by powder X-ray diffractions highlights the chemical compatibility of SCY and ZnO. The phase stability of the composite to water was also improved relative to the pure SCY. Hydrogen permeation fluxes were increased with the ZnO content until 20% (by weight) over which, the flux degradation started to occur, most probably due to the ZnO reduction by hydrogen. As such, SCY-10% ZnO is deemed as the optimized composite. The maximum flux attained using this membrane was 0.039 mL (STP) cm-2 min-1 at 900 °C. Long term evaluation testing for over a 48 hour-period was performed where the SCY-10% ZnO membrane was subjected to alternating cycles of CO2 and N2 sweep gas flows. Despite the significant overall degradation in performance beyond the 3rd cycle, the results show substantial recovery in the performance over the 2nd and 3rd cycles. In contrast with these conventional perovskite and metal dual phase membranes, this work features an attractive concept to develop a proton conducting membrane from SCY-based composite membranes.
Showing items related by title, author, creator and subject.
Enhanced hydrogen permeability and reverse water–gas shift reaction activity via magneli Ti4O7 doping into SrCe0.9Y0.1O3−δ hollow fiber membraneWang, T.; Wang, H.; Meng, X.; Meng, B.; Tan, X.; Sunarso, J.; Liu, Shaomin (2017)Hydrogen proton conducting perovskite-based hollow fiber membrane is an attractive hydrogen separation technology that shows higher stability relative to Pd-based membranes above 800 °C. One of the challenges towards high ...
Enhanced hydrogen permeability and reverse water-gas shift reaction activity via magneli Ti4O7 doping into SrCe0.9Y0.1O3-delta hollow fiber membraneWang, T.; Wang, H.; Meng, X.; Meng, B.; Tan, X.; Sunarso, J.; Liu, Shaomin (2017)Hydrogen proton conducting perovskite-based hollow fiber membrane is an attractive hydrogen separation technology that shows higher stability relative to Pd-based membranes above 800 °C. One of the challenges towards high ...
Perovskite-based mixed protonic-electronic conducting membranes for hydrogen separation: Recent status and advancesWang, H.; Wang, X.; Meng, B.; Tan, X.; Loh, K.; Sunarso, J.; Liu, Shaomin (2017)Hydrogen share in the energy market has increased significantly in line with greater demand for zero emission fuel and the development of novel production routes via renewable resources. The application of mixed ...