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    Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues

    235777_235777.pdf (1.791Mb)
    Access Status
    Open access
    Authors
    Vaughan, Jeffrey
    Carter, Damien
    Rohl, Andrew
    Ogden, Mark
    Skelton, B.
    Simpson, Peter
    Brown, David
    Date
    2015
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Vaughan, J. and Carter, D. and Rohl, A. and Ogden, M. and Skelton, B. and Simpson, P. and Brown, D. 2015. Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues. Dalton Transactions. 45 (4): pp. 1484-1495.
    Source Title
    Dalton Trans
    DOI
    10.1039/c5dt04213e
    School
    Nanochemistry Research Institute
    URI
    http://hdl.handle.net/20.500.11937/23959
    Collection
    • Curtin Research Publications
    Abstract

    Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms.

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