Curtin University Homepage
  • Library
  • Help
    • Admin

    espace - Curtin’s institutional repository

    JavaScript is disabled for your browser. Some features of this site may not work without it.
    View Item 
    • espace Home
    • espace
    • Curtin Research Publications
    • View Item
    • espace Home
    • espace
    • Curtin Research Publications
    • View Item

    Palladium complexes of o-xylyl-linked alkoxybenzimidazolin-2-ylidenes: interesting structural conformations and application as pre-catalysts

    129661_Palladium%20complexes%20of%20o-xylyl-linked.pdf (150.4Kb)
    Access Status
    Open access
    Authors
    Baker, M.
    Brown, David
    Simpson, P.
    Skelton, B.
    White, A.
    Date
    2009
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Baker, Murray and Brown, David and Simpson, Peter and Skelton, Brian and White, Allan. 2009. Palladium complexes of o-xylyl-linked alkoxybenzimidazolin-2-ylidenes: interesting structural conformations and application as pre-catalysts. Dalton Transactions. 2009 (35): pp. 7294-7307.
    Source Title
    Dalton Transactions
    DOI
    10.1039/b908613g
    ISSN
    14779226
    Faculty
    Department of Applied Chemistry
    Nanochemistry Research Institute
    School of Science
    Faculty of Science and Engineering
    School
    Nanochemistry Research Institute (Research Institute)
    Remarks

    The link to the journal's home page is: http://www.rsc.org/publishing/journals/DT/Index.asp

    URI
    http://hdl.handle.net/20.500.11937/26683
    Collection
    • Curtin Research Publications
    Abstract

    New PdBr2-bis(N-heterocyclic carbene) complexes derived from 4,7-dibutoxybenzimidazole and 5,6-dibutoxybenzimidazole have been synthesized and structurally and spectroscopically characterized.The complexes show much greater solubility compared to the parent complex derived from benzimidazole, and interesting structural characteristics dependent on the position of the butoxy substituents. The complexes display high activities in the coupling of aryl iodides in the Mizoroki-Heckreaction and moderate activities in the Suzuki-Miyaura coupling of inactivated aryl bromides at low catalyst loadings, although activity differences between pre-catalysts has been observed. Structuralstudies suggest electronic effects within the complexes to be strongly affected by steric interactions between the hydrogen atoms of the o-xylyl bridges and the benzimidazole components and their substituents.

    Related items

    Showing items related by title, author, creator and subject.

    • Complex Adaptive Systems and Conversation Analysis: A New Perspective for Consumer Behaviour Research?
      Whiteley, Jervis (2002)
      The research question for this study is “Can concepts from complex adaptive systems and conversation analysis be used to research consumer behaviour?" This is, primarily, a theoretical question. After a wide-ranging ...
    • Near consensus complex linear and nonlinear social networks
      Ling, B.; Ho, C.; Wang, L.; Teo, Kok Lay; Tse, C.k; Dai, Q. (2014)
      Some of the nodes of complex social networks may support for a given proposal, while the rest of the nodes may be against the given proposal. Even though all the nodes support for or are against the given proposal, the ...
    • A primary study of the Jilin-Heilongjiang high-pressure metamorphic belt: Evidence and tectonic implications
      Zhou, Jian-Bo; Han, J.; Wilde, Simon; Guo, X.; Zeng, W.; Cao, J. (2013)
      Jilin-Heilongjiang high-pressure metamorphic belt (Ji-Hei HP Belt), around western and southern margin of the Jiamusi-Khanka block, is the high-pressure metamorphic belt with the accretionary complex due to the subduction ...
    Advanced search

    Browse

    Communities & CollectionsIssue DateAuthorTitleSubjectDocument TypeThis CollectionIssue DateAuthorTitleSubjectDocument Type

    My Account

    Admin

    Statistics

    Most Popular ItemsStatistics by CountryMost Popular Authors

    Follow Curtin

    • 
    • 
    • 
    • 
    • 

    CRICOS Provider Code: 00301JABN: 99 143 842 569TEQSA: PRV12158

    Copyright | Disclaimer | Privacy statement | Accessibility

    Curtin would like to pay respect to the Aboriginal and Torres Strait Islander members of our community by acknowledging the traditional owners of the land on which the Perth campus is located, the Whadjuk people of the Nyungar Nation; and on our Kalgoorlie campus, the Wongutha people of the North-Eastern Goldfields.