In situ high pressure NMR study of the direct synthesis of NaAlH 4
dc.contributor.author | Humphries, Terry | |
dc.contributor.author | Birkmire, D. | |
dc.contributor.author | Hauback, B. | |
dc.contributor.author | Sean McGrady, G. | |
dc.contributor.author | Jensen, C. | |
dc.date.accessioned | 2017-01-30T13:01:57Z | |
dc.date.available | 2017-01-30T13:01:57Z | |
dc.date.created | 2015-10-29T04:09:52Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Humphries, T. and Birkmire, D. and Hauback, B. and Sean McGrady, G. and Jensen, C. 2013. In situ high pressure NMR study of the direct synthesis of NaAlH 4 . Physical Chemistry Chemical Physics. 15 (17): pp. 6179-6181. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/27922 | |
dc.identifier.doi | 10.1039/c3cp50777g | |
dc.description.abstract |
The direct synthesis of NaAlH4 has been studied, for the first time, by in situ27Al and 23Na wide-line NMR spectroscopy using high pressure NMR apparatus. Na3AlH6 formation is observed within two minutes of hydrogen addition, while NaAlH4 is detected after a total of four minutes. This indicates the formation of the hexahydride does not proceed to completion before the formation of the tetrahydride ensues. © 2013 the Owner Societies. | |
dc.title | In situ high pressure NMR study of the direct synthesis of NaAlH 4 | |
dc.type | Journal Article | |
dcterms.source.volume | 15 | |
dcterms.source.number | 17 | |
dcterms.source.startPage | 6179 | |
dcterms.source.endPage | 6181 | |
dcterms.source.issn | 1463-9076 | |
dcterms.source.title | Physical Chemistry Chemical Physics | |
curtin.department | Department of Physics and Astronomy | |
curtin.accessStatus | Fulltext not available |
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