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dc.contributor.authorAndrews, P.
dc.contributor.authorBlair, M.
dc.contributor.authorFraser, B.
dc.contributor.authorJunk, P.
dc.contributor.authorMassi, Massimiliano
dc.contributor.authorTuck, K.
dc.date.accessioned2017-01-30T13:04:46Z
dc.date.available2017-01-30T13:04:46Z
dc.date.created2012-12-03T07:24:54Z
dc.date.issued2006
dc.identifier.citationAndrews, Philip C. and Blair, Michael and Fraser, Benjamin H. and Junk, Peter C. and Massi, Massimiliano and Tuck, Kellie L.. 2006. Water soluble lanthanoid benzoate complexes for the kinetic separation of cis/trans-limonene oxide. Tetrahedron: Asymmetry 17 (19): pp. 2833-2838.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/28389
dc.identifier.doi10.1016/j.tetasy.2006.10.026
dc.description.abstract

A new class of water soluble, environmentally friendly, lanthanoid 3,5-diacetamidobenzoate complexes (Ln = La, Gd, Yb) have been synthesized. The La and Gd complexes selectively catalyse hydrolysis of the cis-isomer of limonene oxide allowing for the separation of the trans-isomer (> 98:2 dr) in up to 74% yield. Comparative studies with the corresponding chlorides and triflates reveal the lanthanoid benzoate complexes to be more active than the chlorides, but less active, though more selective, than the triflates

dc.publisherPERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
dc.subjectRESOLUTION
dc.subjectORGANIC-SYNTHESIS
dc.subjectCATALYSIS
dc.subjectLIGANDS
dc.subjectEPOXIDES
dc.subjectTRIFLATE
dc.titleWater soluble lanthanoid benzoate complexes for the kinetic separation of cis/trans-limonene oxide
dc.typeJournal Article
dcterms.source.volume17
dcterms.source.number19
dcterms.source.startPage2833
dcterms.source.endPage2838
dcterms.source.issn09574166
dcterms.source.titleTetrahedron: Asymmetry
curtin.department
curtin.accessStatusFulltext not available


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