Selective oxidation of cyclopentene catalyzed by Pd(CH3COO) 2-NPMoV under oxygen atmosphere
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The selective oxidation of cyclopentene to cyclopentanone catalyzed by Pd(CH3COO)2-NPMoV was investigated under atmospheric oxygen in aqueous acetonitrile acidified by CH3SO3H. It was shown that the conversion of cyclopentene and the yield of cyclopentanone was nearly 100% and 94.6%, respectively, under the optimized reaction condition. © 2008 Springer Science+Business Media, LLC.