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    Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene

    238941_238941.pdf (472.3Kb)
    Access Status
    Open access
    Authors
    Driscoll, C.
    Skelton, B.
    Massi, Massimiliano
    Ogden, Mark
    Date
    2016
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Driscoll, C. and Skelton, B. and Massi, M. and Ogden, M. 2016. Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene. Supramolecular Chemistry. 28 (5-6): pp. 567-574.
    Source Title
    Supramolecular Chemistry
    DOI
    10.1080/10610278.2015.1136744
    ISSN
    1061-0278
    School
    Nanochemistry Research Institute
    Remarks

    This is an Author's Original Manuscript of an article published by Taylor & Francis in Supramolecular Chemistry on 29/01/2016 available online at <a href="http://www.tandfonline.com/10.1080/10610278.2015.1136744">http://www.tandfonline.com/10.1080/10610278.2015.1136744</a>

    URI
    http://hdl.handle.net/20.500.11937/28499
    Collection
    • Curtin Research Publications
    Abstract

    Lanthanoid complexes of a tetra-amide substituted calix[4]arene in the cone conformation are characterised by single crystal X-ray structure determination. The structural analysis shows that the metal ions are coordinated to the calixarene through the eight O donor atoms, along with one aqua ligand which is located within the cavity of the calixarene. The calixarene ligand was covalently incorporated into a polymethylmethacrylate monolith through p-allyl functional groups, followed by loading with a range of lanthanoid cations giving rise to light-emitting materials. The emission from the hydrid materials was found to be comparable to the solution phase emission.

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