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    A new binding geometry for an ortho-xylylene-linked bis(NHC)cyclophane: a ruthenium(II) complex with a chelating (g1-NHC)2:g6-arene ligand

    131650_13572_A new binding geometry for an ortho-xylyene-linked bis_NHC_cyclophane.pdf (425.6Kb)
    Access Status
    Open access
    Authors
    Baker, M.
    Brown, David
    Haque, R.
    Skelton, B.
    White, A.
    Date
    2010
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Baker, Murray V. and Brown, David H. and Haque, Rosenani A. and Skelton, Brian W. and White, Allan H. 2010. A new binding geometry for an ortho-xylylene-linked bis(NHC)cyclophane: a ruthenium(II) complex with a chelating (η1-NHC)2:η6-arene ligand. Dalton Tranactions 39: pp. 70-72.
    Source Title
    Dalton Tranactions
    DOI
    10.1039/b916498g
    ISSN
    1477-9226
    Faculty
    Nanochemistry Research Institute (NRI)
    Faculty of Science and Engineering
    School
    Nanochemistry Research Institute (Research Institute)
    URI
    http://hdl.handle.net/20.500.11937/28799
    Collection
    • Curtin Research Publications
    Abstract

    Using two different reaction procedures, a Ru(II) complex has been isolated that contains an ortho-xylylene-linked bis(NHC)cyclophane (NHC = N-heterocyclic carbene) that binds to the Ru centre through two carbene carbons and one of the arene rings in an η6-mode.

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