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A new binding geometry for an ortho-xylylene-linked bis(NHC)cyclophane: a ruthenium(II) complex with a chelating (g1-NHC)2:g6-arene ligand

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Authors
Baker, M.
Brown, David
Haque, R.
Skelton, B.
White, A.
Date
2010
Type
Journal Article
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Abstract

Using two different reaction procedures, a Ru(II) complex has been isolated that contains an ortho-xylylene-linked bis(NHC)cyclophane (NHC = N-heterocyclic carbene) that binds to the Ru centre through two carbene carbons and one of the arene rings in an η6-mode.

Citation
Baker, Murray V. and Brown, David H. and Haque, Rosenani A. and Skelton, Brian W. and White, Allan H. 2010. A new binding geometry for an ortho-xylylene-linked bis(NHC)cyclophane: a ruthenium(II) complex with a chelating (η1-NHC)2:η6-arene ligand. Dalton Tranactions 39: pp. 70-72.
Source Title
Dalton Tranactions
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DOI
Faculty
Nanochemistry Research Institute (NRI)
Faculty of Science and Engineering
Department
Nanochemistry Research Institute (Research Institute)
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