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    Heteroatom-modulated switching of photocatalytic hydrogen and oxygen evolution preferences of anatase TiO 2 microspheres

    Access Status
    Fulltext not available
    Authors
    Liu, G.
    Pan, Jian
    Yin, L.
    Irvine, J.
    Li, F.
    Tan, J.
    Wormald, P.
    Cheng, H.
    Date
    2012
    Type
    Journal Article
    
    Metadata
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    Citation
    Liu, G. and Pan, J. and Yin, L. and Irvine, J. and Li, F. and Tan, J. and Wormald, P. et al. 2012. Heteroatom-modulated switching of photocatalytic hydrogen and oxygen evolution preferences of anatase TiO 2 microspheres. Advanced Functional Materials. 22 (15): pp. 3233-3238.
    Source Title
    Advanced Functional Materials
    DOI
    10.1002/adfm.201200414
    ISSN
    1616-301X
    School
    Fuels and Energy Technology Institute
    URI
    http://hdl.handle.net/20.500.11937/29318
    Collection
    • Curtin Research Publications
    Abstract

    Understanding and manipulating the two half-reactions of photoinduced electron reduction and hole oxidation are key to designing and constructing efficient photocatalysts. Here, how the spatial distribution of the heteroatom modulates photocatalytic reduction (hydrogen evolution) and oxidation (oxygen evolution) reaction preferences is investigated by moving boron from the core to the shell of an anatase TiO 2 microsphere along [001] via thermal diffusion control. The preference towards photocatalytic hydrogen and oxygen producing reactions from splitting water can be switched by creating a shell with an interstitial B s+ (s = 3) gradient in the TiO;bsubesub microsphere. This switching stems from the downward shift of electronic band edges of the shell by a band bending effect that originates from the extra electrons coming from the interstitial B;bsupumlesup. These results create new opportunities for designing and constructing efficient photocatalysts by spatial heteroatom engineering. By moving heteroatom boron from the core to the shell of an anatase TiO;bsubesub microsphere via thermal diffusion control, the photocatalysis reaction preferences towards hydrogen and oxygen evolution from water splitting can be sensitively switched. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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