Factors influencing the synthesis and the post-modification of PEGylated pentafluorophenyl acrylate containing copolymers
MetadataShow full item record
Copolymerization reactions involving oligoethylene glycol acrylate (OEGA) or diethylene glycol acrylate (DEGA) with pentafluorophenyl acrylate (PFPA) have been performed by reversible addition fragmentation transfer (RAFT) polymerization. The effect of the reaction conditions on the nucleophilic acyl substitution reactions of PFPA was studied using a model amine (furfuryl amine). The resulting PEG/PFP functional copolymers were then used as scaffolds to produce a library of polymers by reaction with a range of amines.
Showing items related by title, author, creator and subject.
Production of acrylic acid through nickel-mediated coupling of ethylene and carbon dioxide - A DFT studyGraham, D.; Mitchell, C.; Bruce, M.; Metha, G.; Bowie, J.; Buntine, Mark (2007)The production of acrylic acid (CH2=CHCO2H) via homogeneous nickel-mediated coupling of ethylene (CH2=CH2) and carbon dioxide (CO2) is industrially unattractive at present due to its stoichiometric, rather than catalytic, ...
Isolation and characterization of l-tryptophan ammonia lyase from rubrivivax benzoatilyticus strain ja2Kumavath, R.; Ramana, C.; Sasikala, C.; Barh, D.; Kumar, Alan Prem; Azevedo, V. (2015)© 2015 Bentham Science Publishers.Ammonia lyase belongs to the family of enzymes that catalyzes the deamination of amino acids. Depending on the relative activity towards the substrates, L-tryptophan ammonia lyase converts ...
Thiol-Michael coupling chemistry: Facile access to a library of functional exo-7-oxanorbornenes and their ring-opening metathesis (co)polymerizationLiu, M.; Van Hensbergen, J.; Burford, R.; Lowe, Andrew (2012)The nucleophile initiated thiol-Michael reaction of a wide range of mono and multifunctional thiols with a novel acrylic exo-7-oxanorbornene is described. We highlight how this process affords ready access to a large ...