Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching
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Authors
Zhang, W.
Zhao, Y.
Malgras, V.
Ji, Q.
Jiang, D.
Qi, R.
Ariga, K.
Yamauchi, Y.
Liu, Jian
Jiang, J.
Hu, M.
Date
2016Type
Journal Article
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Zhang, W. and Zhao, Y. and Malgras, V. and Ji, Q. and Jiang, D. and Qi, R. and Ariga, K. et al. 2016. Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching. Angewandte Chemie - International Edition. 55 (29): pp. 8228-8234.
Source Title
Angewandte Chemie - International Edition
ISSN
School
Department of Chemical Engineering
Collection
Abstract
Metal cyanide coordination compounds are recognized as promising candidates for broad applications because of their tailorable and adjustable frameworks. Developing the nanostructure of a coordination compound may be an effective way to enhance the performance of that material in application-based roles. A controllable preferential etching method is described for synthesis of monocrystalline Prussian blue analogue (PBA) nanoframes, without the use of organic additives. The PBA nanoframes show remarkable rate performance and cycling stability for sodium/lithium ion insertion/extraction.