A cobalt-free layered oxide as an oxygen reduction catalyst for intermediate-temperature solid oxide fuel cells
dc.contributor.author | Jiang, S. | |
dc.contributor.author | Zhou, W. | |
dc.contributor.author | Sunarso, J. | |
dc.contributor.author | Ran, R. | |
dc.contributor.author | Shao, Zongping | |
dc.date.accessioned | 2017-01-30T13:38:58Z | |
dc.date.available | 2017-01-30T13:38:58Z | |
dc.date.created | 2015-12-10T04:26:13Z | |
dc.date.issued | 2015 | |
dc.identifier.citation | Jiang, S. and Zhou, W. and Sunarso, J. and Ran, R. and Shao, Z. 2015. A cobalt-free layered oxide as an oxygen reduction catalyst for intermediate-temperature solid oxide fuel cells. International Journal of Hydrogen Energy. 40 (45): pp. 15578-15584. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/33737 | |
dc.identifier.doi | 10.1016/j.ijhydene.2015.09.097 | |
dc.description.abstract |
© 2015 Hydrogen Energy Publications, LLC. A cobalt-free layered oxide-Sr4Fe6O13-d is synthesized and characterized for application as a cathode of intermediate temperature solid oxide fuel cells. High temperature powder x-ray diffraction, oxygen temperature programmed desorption and electrochemical impedance spectroscopy are employed to evaluate the temperature-dependent crystal structure and oxygen reduction reaction (ORR) activity of Sr4Fe6O13-d. The oxide exhibits a single phase between room temperature and 1050 °C with low thermal expansion coefficient. The drawback of this oxide lies on its low ORR activity which is likely due to its layered structure which favors oxygen ionic transport two-dimensionally in the ac plane along the layered oxide layer. We show here that the original ORR activity can be improved by adjusting the phase compositions through an oxygen-deficient calcination process. An area specific resistance of 0.139 O cm2 at 700 °C is attained by calcining Sr4Fe6O13-d at 900 °C with ~66.2 wt% of perovskite phase in the composite material. | |
dc.title | A cobalt-free layered oxide as an oxygen reduction catalyst for intermediate-temperature solid oxide fuel cells | |
dc.type | Journal Article | |
dcterms.source.volume | 40 | |
dcterms.source.number | 45 | |
dcterms.source.startPage | 15578 | |
dcterms.source.endPage | 15584 | |
dcterms.source.issn | 0360-3199 | |
dcterms.source.title | International Journal of Hydrogen Energy | |
curtin.department | Department of Chemical Engineering | |
curtin.accessStatus | Fulltext not available |
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