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dc.contributor.authorGaudillère, C.
dc.contributor.authorOlivier, L.
dc.contributor.authorVernoux, P.
dc.contributor.authorZhang, C.
dc.contributor.authorShao, Zongping
dc.contributor.authorFarrusseng, D.
dc.date.accessioned2017-01-30T13:41:16Z
dc.date.available2017-01-30T13:41:16Z
dc.date.created2016-09-12T08:36:55Z
dc.date.issued2010
dc.identifier.citationGaudillère, C. and Olivier, L. and Vernoux, P. and Zhang, C. and Shao, Z. and Farrusseng, D. 2010. Alternative perovskite materials as a cathode component for intermediate temperature single-chamber solid oxide fuel cell. Journal of Power Sources. 195 (15): pp. 4758-4764.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/34107
dc.identifier.doi10.1016/j.jpowsour.2010.02.058
dc.description.abstract

This paper exploits the suitability of three perovskite materials Ba0.5Sr0.5Co0.8Fe0.2O3- d (BSCF), GdBaCo2O5+d (GBC) and Ba0.5Sr0.5Mn0.7Fe0.3O3- d (BSMF) as SOFC cathodes in the single-chamber configuration operating at the intermediate temperature range. TG analysis showed high thermal stability depending on the crystalline phases of the materials. The catalytic activity of these three materials for hydrocarbon conversion was investigated under a realistic feed, i.e. with hydrocarbon, oxygen, water and carbon dioxide. Electrochemical impedance spectroscopy of the various cathodes tested in symmetric cell configuration revealed a B-site dependence of the electrode catalytic activity for oxygen reduction. High temperature (1000 °C) powder reactivity tests over a gadolinium doped-ceria (CGO) and perovskite cathode revealed excellent chemical compatibility of BSMF and CGO. Catalytic tests associated with thermal and structural characterization attest to the suitability of these materials in the single-chamber configuration. © 2010 Elsevier B.V. All rights reserved.

dc.publisherElsevier SA
dc.titleAlternative perovskite materials as a cathode component for intermediate temperature single-chamber solid oxide fuel cell
dc.typeJournal Article
dcterms.source.volume195
dcterms.source.number15
dcterms.source.startPage4758
dcterms.source.endPage4764
dcterms.source.issn0378-7753
dcterms.source.titleJournal of Power Sources
curtin.departmentDepartment of Chemical Engineering
curtin.accessStatusFulltext not available


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