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    Characterization of the pore structure of metakaolin-derived geopolymers by neutron scattering and electron microscopy

    173601_173601.pdf (813.7Kb)
    Access Status
    Open access
    Authors
    Maitland, Clinton
    Buckley, Craig
    O'Connor, Brian
    Butler, P.
    Hart, Robert
    Date
    2011
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Maitland, C. F. and Buckley, C. E. and O'Connor, B. H. and Butler, P. D. and Hart, R. D. 2011. Characterization of the pore structure of metakaolin-derived geopolymers by neutron scattering and electron microscopy. Journal of Applied Crystallography. 44 (4): pp. 697-707.
    Source Title
    Journal of Applied Crystallography
    DOI
    10.1107/S0021889811021078
    ISSN
    0021-8898
    School
    Department of Imaging and Applied Physics
    URI
    http://hdl.handle.net/20.500.11937/34628
    Collection
    • Curtin Research Publications
    Abstract

    The pore-solid structure of selected high-compressive-strength metakaolin geopolymers has been characterized to facilitate quantitative prediction of their physical properties. Geopolymers are multiphase materials with pore widths ranging from subnanometre to several tenths of a millimetre. Ultramicrotoming of resin-embedded grains was found to be an effective method for producing electron-transparent sections. Scanning and transmission electron microscopy showed the existence of a bi-level pore system and heterogeneity of the pore morphology. Ultra-small-angle neutron scattering, of sufficiently thin specimens, was found to be useful in detecting the length scales on which statistically significant structural changes occur as the geopolymer chemical composition is varied. Contrast variation experiments confirmed that the small-angle neutron scattering from an Si:Al:Na = 2.5:1:1.2 geopolymer before and after dehydration was dominated by scattering from pores. These experiments suggested the presence of closed (under current experimental conditions) pores in the dehydrated geopolymer. A three-phase analysis was developed for this system, and the scattering of the solid, open pore and closed pore phases was determined as a function of scattering length density ρ. The scattering from all three phases had the same q dependence over the range of likely ρ within the uncertainties.A lower limit of 4.21 (6) × 1010 cm-2 was determined for the scattering length density ρw of the nondehydrated geopolymer by assuming the pore fluid to be water. This scattering length density is significantly higher than the expected value of approximately 3.4 × 1010 cm-2. Small-angle neutron scattering from the dehydrated and nondehydrated Si:Al:Na = 2.5:1:1.2 geopolymer showed that dehydration does not cause a severe change in morphology of the nanoporosity on the length scale probed.

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