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Diol-functionalised benzoates as novel linkers for the formation of coordination polymers

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Authors
Andrews, P.
Forsyth, C.
Fraser, B.
Junk, P.
Massi, Massimiliano
Silberstein, Morry
Date
2007
Type
Journal Article

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Andrews, Philip C. and Forsyth, Craig M. and Fraser, Benjamin H. and Junk, Peter C. and Massi, Massimiliano and Silberstein, Morry. 2007. Diol-functionalised benzoates as novel linkers for the formation of coordination polymers. CrystEngComm 9 (4): pp. 282-285.
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CrystEngComm
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Abstract

Reaction of La(HCO3)(3) with enantiomerically pure (R)-4-(2,3-dihydroxypropoxy) benzoic acid (DBAH) gives the neutral complex La(DBA)(3), which on heating undergoes self-organisation into a 1D coordination polymer, [La-2(DBA)(6)(H2O)(4)](infinity), as determined by X-ray crystallography.