Polarization Promoted Chemical Reaction between Ba0.5Sr0.5Co0.8Fe0.2O3-δ Cathode and Ceria Based Electrolytes of Solid Oxide Fuel Cells
dc.contributor.author | Yung, H. | |
dc.contributor.author | Jian, L. | |
dc.contributor.author | Jiang, San Ping | |
dc.date.accessioned | 2017-01-30T13:51:01Z | |
dc.date.available | 2017-01-30T13:51:01Z | |
dc.date.created | 2012-11-18T20:00:21Z | |
dc.date.issued | 2012 | |
dc.identifier.citation | Yung, Hoi and Jian, Li and Jiang, San ping. 2012. Polarization Promoted Chemical Reaction between Ba0.5Sr0.5Co0.8Fe0.2O3-δ Cathode and Ceria Based Electrolytes of Solid Oxide Fuel Cells. Journal of the Electrochemical Society. 159 (11): pp. F794-F798. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/35663 | |
dc.identifier.doi | 10.1149/2.026212jes | |
dc.description.abstract |
The chemical compatibility of Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) electrodes with ceria based electrolytes is investigated under solid oxide fuel cell (SOFC) operation conditions. BSCF reacts with both Ce0.9Gd0.1O1.95 (GDC) and Ce0.8Sm0.2O1.95 (SDC) at 900°C, forming barium cerate (BaxCe1-yMyO3, where M= Gd or Sm). Under cathodic current passage, the interaction between BSCF and ceria-based electrolyte takes place at temperatures as low as 700°C, forming Ba-containing particles (probably barium cerate) at the electrode/electrolyte interface. The results show that cathodic polarization promotes the chemical reaction between BSCF and ceria-based electrolyte. The accelerated reaction between BSCF and ceria is most likely related to the Ba segregation under influence of polarization and/or temperature. | |
dc.publisher | The Electrochemical Society, Inc | |
dc.subject | solid oxide fuel cells | |
dc.title | Polarization Promoted Chemical Reaction between Ba0.5Sr0.5Co0.8Fe0.2O3-δ Cathode and Ceria Based Electrolytes of Solid Oxide Fuel Cells | |
dc.type | Journal Article | |
dcterms.source.volume | 159 | |
dcterms.source.number | 11 | |
dcterms.source.startPage | F794 | |
dcterms.source.endPage | F798 | |
dcterms.source.issn | 0013-4651 | |
dcterms.source.title | Journal of the Electrochemical Society | |
curtin.department | ||
curtin.accessStatus | Fulltext not available |