Crystallographic Determination of Three Ni-a-Hydroxyoxime-Carboxylic Acid Synergist Complexes
| dc.contributor.author | Barnard, K. | |
| dc.contributor.author | Nealon, Gareth | |
| dc.contributor.author | Ogden, Mark | |
| dc.contributor.author | Skelton, B. | |
| dc.date.accessioned | 2017-01-30T13:57:37Z | |
| dc.date.available | 2017-01-30T13:57:37Z | |
| dc.date.created | 2010-11-28T20:02:56Z | |
| dc.date.issued | 2010 | |
| dc.identifier.citation | Barnard, Keith and Nealon, Gareth and Ogden, Mark and Skelton, Brian. 2010. Crystallographic Determination of Three Ni-a-Hydroxyoxime-Carboxylic Acid Synergist Complexes. Solvent Extraction and Ion Exchange. 28 (6): pp. 778-792. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/36764 | |
| dc.identifier.doi | 10.1080/07366299.2010.515169 | |
| dc.description.abstract |
X-ray crystal structures of three dicarboxylato-bis-a-hydroxyoximenickel(II) complexes have been obtained. These contain a short chained (C8) analogue of LIX®63 hydroxyoxime, along with either benzoate, isobutyrate or propionate. All have pseudo-octahedral structures with monodentate carboxylate anions located cis to one another and neutral, chelating a-hydroxyoxime ligands. Intra-molecular hydrogen bonding between each anionic acid's carboxylate group and an adjacent oxime hydroxyl group is evident. Inter-molecular hydrogen bonding is also observed. These provide the first definitive structural elucidation of the types of nickel complexes that could be formed during synergistic extraction by LIX®63 and carboxylic acids. | |
| dc.publisher | Taylor and Francis Group | |
| dc.subject | synergist | |
| dc.subject | 5 | |
| dc.subject | LIX63 | |
| dc.subject | 8-diethyl-7-hydroxydodecan-6-oxime | |
| dc.subject | X-ray | |
| dc.subject | Versatic 10 | |
| dc.subject | crystal structure | |
| dc.subject | synergistic solvent extraction | |
| dc.subject | carboxylic acid | |
| dc.title | Crystallographic Determination of Three Ni-a-Hydroxyoxime-Carboxylic Acid Synergist Complexes | |
| dc.type | Journal Article | |
| dcterms.source.volume | 28 | |
| dcterms.source.startPage | 778 | |
| dcterms.source.endPage | 792 | |
| dcterms.source.issn | 07366299 | |
| dcterms.source.title | Solvent Extraction and Ion Exchange | |
| curtin.department | Nanochemistry Research Institute (Research Institute) | |
| curtin.accessStatus | Open access | |
| curtin.faculty | Nanochemistry Research Institute (NRI) | |
| curtin.faculty | Faculty of Science and Engineering |