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dc.contributor.authorD'Alessio, D.
dc.contributor.authorLombardo, D.
dc.contributor.authorVaughan, J.
dc.contributor.authorSkelton, B.
dc.contributor.authorBarnard, K.
dc.contributor.authorOgden, Mark
dc.date.accessioned2017-01-30T14:02:35Z
dc.date.available2017-01-30T14:02:35Z
dc.date.created2015-10-29T04:09:09Z
dc.date.issued2015
dc.identifier.citationD'Alessio, D. and Lombardo, D. and Vaughan, J. and Skelton, B. and Barnard, K. and Ogden, M. 2015. Structural variations in metal complexes of a tertiary α-hydroxyoxime. Dalton Transactions. 44 (16): pp. 7163-7168.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/37410
dc.identifier.doi10.1039/c4dt03393k
dc.description.abstract

Despite the long term interest in hydroxyoximes as metal ion extractants, there is a lack of information on the possible coordination modes these ligands can assume, particularly in concert with a co-ligand. This is pertinent to the use of these extractants in synergistic systems, where a combination of extractants can achieve commercially useful results. We report here the structures of some metal complexes (M = Mn, Co, Ni, Cu, and Zn) with (1-hydroxycyclohexyl)-phenyl ketone oxime. The results demonstrate that this ligand can support complexes ranging from mononuclear to trinuclear, in association with anionic and neutral co-ligands in some cases. While these results have been obtained in the solid state, they illustrate a range of possible species that may be formed in extractant solutions.

dc.publisherRoyal Society of Chemistry
dc.titleStructural variations in metal complexes of a tertiary α-hydroxyoxime
dc.typeJournal Article
dcterms.source.volume44
dcterms.source.number16
dcterms.source.startPage7163
dcterms.source.endPage7168
dcterms.source.issn1477-9226
dcterms.source.titleDalton Transactions
curtin.departmentDepartment of Chemistry
curtin.accessStatusOpen access


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