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    Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion?

    199520_199520.pdf (1.197Mb)
    Access Status
    Open access
    Authors
    Glasser, Leslie
    Jenkins, H.D.
    Klapotke, T.
    Date
    2014
    Type
    Journal Article
    
    Metadata
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    Citation
    Glasser, L. and Jenkins, H.D. and Klapotke, T. 2014. Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? Zeitschrift für anorganische und allgemeine Chemie. 640 (7): pp. 1297-1299.
    Source Title
    Zeitschrift für anorganische und allgemeine Chemie
    DOI
    10.1002/zaac.201400007
    ISSN
    1521-3749
    Remarks

    This is the accepted version of the following article: Glasser, L. and Jenkins, H.D. and Klapotke, T. 2014. Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? Zeitschrift für anorganische und allgemeine Chemie. 640 (7): pp. 1297-1299, which has been published in final form at http://doi.org/10.1002/zaac.201400007

    URI
    http://hdl.handle.net/20.500.11937/38828
    Collection
    • Curtin Research Publications
    Abstract

    In previous publications we have used volume-based thermodynamics (VBT) to estimate the lattice energies and enthalpies of new high-energy ionic materials. The use of the VBT approach for salts containing non-spherical ions such as the 5,5′-(tetrazolate-1N-oxide) dianion in TKX-50 [bishydroxylammonium 5,5′-(tetrazolate-1N-oxide)] has received some criticism. Herein we show that the VBT approach is suitable for the estimation of lattice energies/enthalpies for such salts.

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