Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion?
Abstract
In previous publications we have used volume-based thermodynamics (VBT) to estimate the lattice energies and enthalpies of new high-energy ionic materials. The use of the VBT approach for salts containing non-spherical ions such as the 5,5′-(tetrazolate-1N-oxide) dianion in TKX-50 [bishydroxylammonium 5,5′-(tetrazolate-1N-oxide)] has received some criticism. Herein we show that the VBT approach is suitable for the estimation of lattice energies/enthalpies for such salts.
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This is the accepted version of the following article: Glasser, L. and Jenkins, H.D. and Klapotke, T. 2014. Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? Zeitschrift für anorganische und allgemeine Chemie. 640 (7): pp. 1297-1299, which has been published in final form at http://doi.org/10.1002/zaac.201400007
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