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    Variation in XANES in biotite as a function of orientation, crystal composition, and metamorphic history

    200860_200860.pdf (5.027Mb)
    Access Status
    Open access
    Authors
    Evans, Katy
    Dyar, M.
    Reddy, Steven
    Lanzirotti, A.
    Adams, D.
    Tailby, N.
    Date
    2014
    Type
    Journal Article
    
    Metadata
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    Citation
    Evans, K. and Dyar, M. and Reddy, S. and Lanzirotti, A. and Adams, D. and Tailby, N. 2014. Variation in XANES in biotite as a function of orientation, crystal composition, and metamorphic history. American Mineralogist. 99 (2-3): pp. 443-457.
    Source Title
    American Mineralogist
    DOI
    10.2138/am.2014.4222
    ISSN
    0003-004X
    School
    Department of Applied Geology
    Remarks

    NOTICE: This is the author’s version of a work in which changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication.

    URI
    http://hdl.handle.net/20.500.11937/39843
    Collection
    • Curtin Research Publications
    Abstract

    Microscale analysis of ferrous:ferric iron ratios in silicate minerals has the potential to constrain geological processes but has proved challenging because textural information and spatial resolution are limited with bulk techniques, and in situ methods have limited spatial resolution. Synchrotron methods, such as XANES, have been hampered by the sensitivity of spectra to crystal orientation and matrix effects. In an attempt to break this nexus, biotites from Tanzania were characterized with a combination of optical microscopy, electron microprobe, Mössbauer analysis, electron backscatter diffraction (EBSD) and X-ray absorption near edge structure (XANES) spectroscopy. Pre-edge and edge characteristics of the FeKa absorption feature were compared to orientation information derived by EBSD and ferric iron content derived from Mössbauer analysis. Statistically significant correlations between measured spectral features and optic/crystallographic orientation were observed for individual samples. However, orientation corrections derived from these correlations did not reduce the uncertainty in Fe3+/Fetot. The observations are consistent with matrix- and ordering-dependency of the XANES features, and further work is necessary if a general formulation for orientation corrections is to be devised.

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