Curtin University Homepage
  • Library
  • Help
    • Admin

    espace - Curtin’s institutional repository

    JavaScript is disabled for your browser. Some features of this site may not work without it.
    View Item 
    • espace Home
    • espace
    • Curtin Research Publications
    • View Item
    • espace Home
    • espace
    • Curtin Research Publications
    • View Item

    Failure modes of hollow core–shell structural active materials during the lithiation–delithiation process

    Access Status
    Fulltext not available
    Authors
    Ma, Z.
    Xie, Z.
    Wang, Y.
    Zhang, P.
    Pan, Y.
    Zhou, Y.
    Lu, Chunsheng
    Date
    2015
    Type
    Journal Article
    
    Metadata
    Show full item record
    Citation
    Ma, Z. and Xie, Z. and Wang, Y. and Zhang, P. and Pan, Y. and Zhou, Y. and Lu, C. 2015. Failure modes of hollow core–shell structural active materials during the lithiation–delithiation process. Journal of Power Sources. 290: pp. 114-122.
    Source Title
    Journal of Power Sources
    DOI
    10.1016/j.jpowsour.2015.05.008
    ISSN
    0378-7753
    School
    Department of Mechanical Engineering
    URI
    http://hdl.handle.net/20.500.11937/40116
    Collection
    • Curtin Research Publications
    Abstract

    Although they may improve the electrochemical performance of lithium-ion batteries, core–shell structural anode materials with high-capacity suffer from large volume expansion and dissolution during lithium-ion intercalation/extraction. To well understand these problems, failure modes are analyzed in core–shell structural active materials of a lithium-ion battery during the lithiation–delithiation process. Taking into account the lithium-ion concentration distribution along the direction of radius, the diffusion-induced stress field is calculated according to a perfectly elastic–plastic model. Based on the strain energy release rate, the critical sizes of core and shell for avoiding surface fracture and interface debonding are determined as a function of the state of charge. Furthermore, the three-dimensional phase diagram is constructed to demonstrate the relationship between the shell thickness, the outer radius of core, and the ratio of outer and inner radii.

    Related items

    Showing items related by title, author, creator and subject.

    • Fabrication of core-shell, yolk-shell and hollow Fe3O4@ carbon microboxes for high-performance lithium-ion batteries
      Tian, H.; Liu, H.; Yang, T.; Veder, J.; Wang, G.; Hu, M.; Wang, Shaobin; Jaroniec, M.; Liu, J. (2017)
      Metal oxide–carbon composites with core–shell, yolk–shell and hollow structures have attracted enormous interest because of their applications in lithium-ion batteries. However, the relationship between structure and ...
    • Failure prediction of high-capacity electrode materials in lithium-ion batteries
      Wang, C.; Ma, Z.; Wang, Y.; Lu, Chunsheng (2016)
      The large volume change during lithium-ion insertion/extraction leads to huge stress and even failure of active materials. To well understand such a problem, the two-phase lithiation process of film and hollow core-shell ...
    • A low resistance and stable lithium-garnet electrolyte interface enabled by a multifunctional anode additive for solid-state lithium batteries
      Cao, Chencheng; Zhong, Yijun ; Chandula Wasalathilake, Kimal; Tadé, Moses O.; Xu, Xiaomin ; Rabiee, H.; Roknuzzaman, M.; Rahman, R.; Shao, Zongping (2022)
      Solid-state batteries (SSBs) have attracted considerable attention due to their high intrinsic stability and theoretical energy density. As the core part, garnet electrolyte has been extensively investigated due to its ...
    Advanced search

    Browse

    Communities & CollectionsIssue DateAuthorTitleSubjectDocument TypeThis CollectionIssue DateAuthorTitleSubjectDocument Type

    My Account

    Admin

    Statistics

    Most Popular ItemsStatistics by CountryMost Popular Authors

    Follow Curtin

    • 
    • 
    • 
    • 
    • 

    CRICOS Provider Code: 00301JABN: 99 143 842 569TEQSA: PRV12158

    Copyright | Disclaimer | Privacy statement | Accessibility

    Curtin would like to pay respect to the Aboriginal and Torres Strait Islander members of our community by acknowledging the traditional owners of the land on which the Perth campus is located, the Whadjuk people of the Nyungar Nation; and on our Kalgoorlie campus, the Wongutha people of the North-Eastern Goldfields.