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dc.contributor.authorBaker, M.
dc.contributor.authorBrown, David
dc.contributor.authorSimpson, P.
dc.contributor.authorSkelton, B.
dc.contributor.authorWhite, A.
dc.date.accessioned2017-01-30T14:43:35Z
dc.date.available2017-01-30T14:43:35Z
dc.date.created2009-04-16T20:02:06Z
dc.date.issued2009
dc.identifier.citationBaker, Murray and Brown, David and Simpson, Peter and Skelton, Brian and White, Allan. 2009. Synthesis and characterisation of (Alkoxybenzimidazolin-2-ylidene) palladium complexes: the effect of ancillary ligands on the behaviour of precatalysts. European Journal of Inorganic Chemistry 2009 (13): pp. 1977-1988.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/40522
dc.identifier.doi10.1002/ejic.200801154
dc.description.abstract

A series of new N-heterocyclic carbene (NHC)-palladium(II) complexes bearing electron-rich benzimidazolin-2-ylidene ligands are described and structurally and spectroscopically characterised. These (benzimidazolin-2-ylidene)palladium complexes bear butoxy groups to increase the solubility and perhaps influence the catalytic activity by increasing the electron density around the metal centre. The effect of varying the ancillary ligands is investigated, although these ligandsdo not appear to significantly alter the activity of the complexes as precatalysts. Preliminary studies indicate the complexes act as precatalysts with moderate activity in the Mizoroki-Heck and Suzuki-Miyaura coupling reactions.

dc.publisherWiley-VCH Verlag GmbH & Co
dc.titleSynthesis and characterisation of (Alkoxybenzimidazolin-2-ylidene) palladium complexes: the effect of ancillary ligands on the behaviour of precatalysts
dc.typeJournal Article
dcterms.source.volume2009
dcterms.source.number13
dcterms.source.startPage1977
dcterms.source.endPage1988
dcterms.source.issn14341948
dcterms.source.titleEuropean Journal of Inorganic Chemistry
curtin.note

Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA

curtin.note

A link to the journal's website is available at: http://www3.interscience.wiley.com/journal/27721/home

curtin.departmentNanochemistry Research Institute (Research Institute)
curtin.accessStatusFulltext not available
curtin.facultySchool of Science
curtin.facultyScience and Engineering


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