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    Designer based Fourier transformed voltammetry: A multi-frequency, variable amplitude, sinusoidal waveform

    135012_135012.pdf (723.9Kb)
    Access Status
    Open access
    Authors
    Tan, Yong-jun
    Stevenson, G.
    Baker, R.
    Elton, D.
    Gillow, K.
    Zhang, Jie
    Bond, A.
    Gavaghan, D.
    Date
    2009
    Type
    Journal Article
    
    Metadata
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    Citation
    Tan, Yong-jun and Stevenson, Gareth P. and Baker, Ruth E. and Elton, Darryl and Gillow, Kathryn and Zhang, Jie and Bond, Alan M. and Gavaghan, David J. 2009. Designer based Fourier transformed voltammetry: A multi-frequency, variable amplitude, sinusoidal waveform. Journal of Electroanalytical Chemistry. 634 (1): pp. 11-21.
    Source Title
    Journal of Electroanalytical Chemistry
    DOI
    10.1016/j.jelechem.2009.07.007
    ISSN
    15726657
    Faculty
    Department of Applied Chemistry
    School of Science and Computing
    Faculty of Science and Engineering
    Remarks

    The link to the journal’s home page is: http://www.elsevier.com/wps/find/journaldescription.cws_home/504087/description#description. Copyright © 2009 Elsevier B.V. All rights reserved

    URI
    http://hdl.handle.net/20.500.11937/4179
    Collection
    • Curtin Research Publications
    Abstract

    Fourier transform methods allow custom-designed complex waveforms to be used in ac voltammetry. Commonly a single wave or sum of sine waves of variable angular frequency but constant amplitude superimposed onto a dc ramp are employed. In the present case, a custom-designed waveform consisting of a combination of eight sine waves is introduced, with the property that each sine wave within the composite waveform has the property where i represents the ith sine wave. Frequencies (and amplitudes) employed in a single experiment cover the range from 34.94 Hz (20 mV) to 1970.01 Hz (2.66 mV). Reversibility is readily detected via use of this designer waveform by noting a constant peak height Ip (wt) for all eight frequencies, whereas Ip (wt) values decrease in a characteristic manner with increasing frequency for a quasi-reversible process or when uncompensated resistance is present, as demonstrated experimentally and theoretically. Importantly, background charging current contributions do not increase to a level that makes measurement of faradaic current difficult at high frequencies and hence charging current is readily corrected for over the entire frequency range of interest.

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