Cu-BTC metal-organic framework as a novel catalyst for low temperature selective catalytic reduction (SCR) of NO by NH3: Promotional effect of activation temperature
dc.contributor.author | Li, C. | |
dc.contributor.author | Shi, Y. | |
dc.contributor.author | Zhang, H. | |
dc.contributor.author | Zhao, Q. | |
dc.contributor.author | Xue, F. | |
dc.contributor.author | Li, Xin Yong | |
dc.date.accessioned | 2017-01-30T14:57:09Z | |
dc.date.available | 2017-01-30T14:57:09Z | |
dc.date.created | 2016-07-06T19:30:16Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Li, C. and Shi, Y. and Zhang, H. and Zhao, Q. and Xue, F. and Li, X.Y. 2016. Cu-BTC metal-organic framework as a novel catalyst for low temperature selective catalytic reduction (SCR) of NO by NH3: Promotional effect of activation temperature. Integrated Ferroelectrics. 172 (1): pp. 169-179. | |
dc.identifier.uri | http://hdl.handle.net/20.500.11937/42055 | |
dc.identifier.doi | 10.1080/10584587.2016.1177385 | |
dc.description.abstract |
Metal-organic framework Cu-BTC was synthesized by hydrothermal method, and was employed as denitrification catalyst for low temperature selective catalytic reduction of NO with NH3 (NH3-SCR). After activated at different temperatures from 180°C to 250°C in vacuum, Cu-BTC samples were characterized by NH3-SCR test, X-ray powder diffraction, thermal analysis, scanning electron microscope and in situ Fourier-transform infrared. NO conversion results revealed that activation temperatures played a significant beneficial effect role in Cu-BTC catalytic performance for low-temperature NH3-SCR reaction. The Cu-BTC catalyst pre-treated at 230°C achieved a complete NO conversion efficiency with large operating-temperature window from 220°C to 280°C. This excellent catalytic activity was mainly attributed to the unsaturated Cu sites in Cu-BTC. The correlation between catalytic property and structure of Cu-BTC was discussed. | |
dc.title | Cu-BTC metal-organic framework as a novel catalyst for low temperature selective catalytic reduction (SCR) of NO by NH3: Promotional effect of activation temperature | |
dc.type | Journal Article | |
dcterms.source.volume | 172 | |
dcterms.source.number | 1 | |
dcterms.source.startPage | 169 | |
dcterms.source.endPage | 179 | |
dcterms.source.issn | 1058-4587 | |
dcterms.source.title | Integrated Ferroelectrics | |
curtin.department | Department of Chemical Engineering | |
curtin.accessStatus | Fulltext not available |
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