Show simple item record

dc.contributor.authorGao, J.
dc.contributor.authorZhang, X.
dc.contributor.authorLu, Y.
dc.contributor.authorLiu, Shaomin
dc.contributor.authorLiu, Jian
dc.date.accessioned2017-01-30T14:58:44Z
dc.date.available2017-01-30T14:58:44Z
dc.date.created2015-10-29T04:09:23Z
dc.date.issued2015
dc.identifier.citationGao, J. and Zhang, X. and Lu, Y. and Liu, S. and Liu, J. 2015. Selective functionalization of hollow nanospheres with acid and base groups for cascade reactions. Chemistry - A European Journal. 21 (20): pp. 7403-7407.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/42298
dc.identifier.doi10.1002/chem.201500532
dc.description.abstract

The inner-surface functionalization of hollow silica spheres has rarely been reported and is still a challenging topic. Herein, we report a deacetalization–Henry cascade reaction catalyzed by dual-functionalized mesoporous silica hollow nanospheres with basic amine groups ([BOND]NH2) on the internal shell and carboxylic acid groups ([BOND]COOH) on the external shell. The selective functionalization has been realized by a combination of “step-by-step post-grafting” and “cationic surfactant-assisted selective etching” strategy. Compared to unisolated catalyst, the selectively isolated acidic and basic dual catalyst provides excellent catalytic performance for the deacetalization–Henry cascade reaction in terms of both activity (>99 %) and selectivity (95 %).

dc.publisherWiley-VCH Verlag
dc.titleSelective functionalization of hollow nanospheres with acid and base groups for cascade reactions
dc.typeJournal Article
dcterms.source.volume21
dcterms.source.number20
dcterms.source.startPage7403
dcterms.source.endPage7407
dcterms.source.issn0947-6539
dcterms.source.titleChemistry - A European Journal
curtin.departmentDepartment of Chemical Engineering
curtin.accessStatusFulltext not available


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record