Show simple item record

dc.contributor.authorFleming, Sean
dc.contributor.authorGutsche, C.
dc.contributor.authorHarrowfield, J.
dc.contributor.authorOgden, Mark
dc.contributor.authorSkelton, B.
dc.contributor.authorStewart, D.
dc.contributor.authorWhite, A.
dc.date.accessioned2017-01-30T15:05:01Z
dc.date.available2017-01-30T15:05:01Z
dc.date.created2008-11-12T23:21:35Z
dc.date.issued2003
dc.identifier.citationFleming, Sean and Gutsche, C. David and Harrowfield, Jack M. and Ogden, Mark I. and Skelton, Brian W. and Stewart, Donald F. and White, Allan H.. 2003. Calixarenes as aryloxides: oligonuclear europium(III) derivatives. Dalton Transactions 2003 (17): 3319-3327.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/43134
dc.description.abstract

Synthetic and structural studies of europium complexes of calix[8]arene, p-t-Bu-calix[7]arene and p-t-Bu-calix-[9]arene are reported. The complex [Eu2(calix[8]arene-6H)(dmso)5] was found to have a similar structure topreviously reported p-t-Bu- and p-nitro-calix[8]arene complexes of the lanthanides. Despite being prepared undersimilar conditions, the complex of p-t-Bu-calix[7]arene was found to be a tetranuclear assembly, formulated as[(HO)2(OCO2)Eu4(p-t-Bu-calix[7]arene-4H)2(dmso)6]. Expanding the ligand to p-t-Bu-calix[9]arene resulted in theisolation of a larger oligonuclear assembly, [(HO)9(H2O)2Eu7(p-t-Bu-calix[9]arene-6H)2(dmso)6]. In contrast to theconsistent structural type found with the calix[8]arene system, however, use of a different solvent (acetone) gave riseto a much simpler species, [Eu2(p-t-Bu-calix[9]arene-3H)2(dmso)4].

dc.publisherRoyal Society of Chemistry
dc.relationhttp://xlink.rsc.org/?DOI=b305041f
dc.relationhttp://www.rsc.org/Publishing/Journals/DT/article.asp?doi=b305041f
dc.subjectlanthanide
dc.subjectcalixarene
dc.subjecteuropium
dc.titleCalixarenes as aryloxides: oligonuclear europium(III) derivatives
dc.typeJournal Article
dcterms.dateSubmitted2007-01-25
dcterms.source.volume2003
dcterms.source.number17
dcterms.source.monthsep
dcterms.source.startPage3319
dcterms.source.endPage3327
dcterms.source.titleDalton Transactions
curtin.digitool.pid19323
curtin.note

This article was originally published by the Royal Society of Chemistry.

curtin.note

It may not be further made available or distributed.

curtin.pubStatusPublished
curtin.refereedTRUE
curtin.departmentNanochemistry Research Institute
curtin.identifierEPR-567
curtin.accessStatusOpen access
curtin.facultyNanochemistry Research Centre


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record