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dc.contributor.authorLow, It Meng
dc.contributor.authorPang, Wei
dc.contributor.editorDongming Zhu
dc.contributor.editorHua-Tay Lin
dc.contributor.editorYanchun Zhou
dc.contributor.editorTaejin Huang
dc.date.accessioned2017-01-30T15:15:48Z
dc.date.available2017-01-30T15:15:48Z
dc.date.created2013-03-03T20:00:22Z
dc.date.issued2012
dc.identifier.citationLow, I.M. and Pang, W.K. 2012. A Comparative Study of Decomposition Kinetics in MAX Phases at Elevated Temperature, in D. Zhu, H. Lin, Y. Zhou and T. Huang (ed), 36th International Conference on Advanced Ceramics and Composites, Jan 22-27 2012, pp. 179-185. Daytona Beach, Florida: Wiley.
dc.identifier.urihttp://hdl.handle.net/20.500.11937/44695
dc.description.abstract

The role of pore microstructures on the susceptibility of MAX phases (Ti3SiC2, Ti3AlC2, Ti2AlC, Ti2AlN2, Ti4AlN3) to thermal dissociation at 1300-1550 °C in high vacuum has been studied using in-situ neutron diffraction. Above 1400 °C, MAX phases decomposed to binary carbide (e.g. TiCx) or binary nitride (e.g. TiNx), primarily through the sublimation of Aelements such as Al or Si, forming in a porous surface layer of MXx. Positive activation energies were determined for decomposed MAX phases with coarse pores but a negative activation energy when the pore size was less than 1.0 µm. The role of pore microstructures on the decomposition kinetics is discussed.

dc.publisherWiley
dc.titleA Comparative Study of Decomposition Kinetics in MAX Phases at Elevated Temperature
dc.typeConference Paper
dcterms.source.startPage179
dcterms.source.endPage185
dcterms.source.titleAdvanced Ceramic Coatings and Materials for Extreme Environments II: Ceramic Engineering and Science Proceedings, Volume 33, Issue 3
dcterms.source.seriesAdvanced Ceramic Coatings and Materials for Extreme Environments II: Ceramic Engineering and Science Proceedings, Volume 33, Issue 3
dcterms.source.isbn9781118205891
dcterms.source.conference36th International Conference on Advanced Ceramics and Composites
dcterms.source.conference-start-dateJan 22 2012
dcterms.source.conferencelocationDaytona Beach, Florida, USA
dcterms.source.placeHoboken, New Jersey, USA
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curtin.accessStatusFulltext not available


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