Using XPS to determine solute solubility in room temperature ionic liquids
| dc.contributor.author | Silvester, Debbie | |
| dc.contributor.author | Broder, T. | |
| dc.contributor.author | Aldous, L. | |
| dc.contributor.author | Hardacre, C. | |
| dc.contributor.author | Crossley, A. | |
| dc.contributor.author | Compton, R. | |
| dc.date.accessioned | 2017-01-30T10:40:27Z | |
| dc.date.available | 2017-01-30T10:40:27Z | |
| dc.date.created | 2015-09-29T01:51:51Z | |
| dc.date.issued | 2007 | |
| dc.identifier.citation | Silvester, D. and Broder, T. and Aldous, L. and Hardacre, C. and Crossley, A. and Compton, R. 2007. Using XPS to determine solute solubility in room temperature ionic liquids. The Analyst. 132: pp. 196-198. | |
| dc.identifier.uri | http://hdl.handle.net/20.500.11937/4632 | |
| dc.identifier.doi | 10.1039/b700212b | |
| dc.description.abstract |
X-Ray Photoelectron Spectroscopy (XPS) was used to quantify the amount of bromide ions present in two samples of [C4mpyrr]Br dissolved in the room temperature ionic liquid (RTIL) [C4mpyrr][N(Tf)2]. One sample was of a known concentration (0.436 Br atom%); the other was a saturated solution. The results obtained from quantitative XPS analysis indicated that the saturated sample had a concentration, or solubility, of 0.90 Br atom% (746 mM) at 298 K, which was then independently confirmed by potential-step chronoamperometry of the same solution. | |
| dc.publisher | The Royal Society of Chemistry | |
| dc.title | Using XPS to determine solute solubility in room temperature ionic liquids | |
| dc.type | Journal Article | |
| dcterms.source.volume | 132 | |
| dcterms.source.startPage | 196 | |
| dcterms.source.endPage | 198 | |
| dcterms.source.issn | 00032654 | |
| dcterms.source.title | The Analyst | |
| curtin.accessStatus | Fulltext not available |